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2 Theoretical framework

2.4 Olive Pomace

2.4.1 Production process

In the olive oil production industry, there are two types of processes, including discontinuous process (traditional pressing) and continuous centrifugation process, the last is subdivided into three-phases centrifugation and two-phases centrifugation. In the Table 2.2 are summarized the input and output descriptions of the continuous and discontinuous olive oil production in order to compare them.

 Discontinuous process: traditional pressing

According to Petrakis (2006), the production process begins with the cleaning of the olives. Initially, a strong airflow from an extraction fan is used, whose purpose is to eliminate leaves, branches and any type of dirt. Afterwards, they are washed with cold water, which comes from recirculation after washing mixed in a certain proportion with fresh water.

The next stage of the process is performed by the hydraulic presses. During this phase of the process, the cells of the olive are teared, releasing the drops of oil. However, not all the oil is released because it is impossible to lacerate all the cells. In addition, amphoteric pseudomembranous which keep the oil in emulsion state, surround the oil drops, preventing the extraction.

The olive paste derived from the crushing is subject to the malaxation phase. At this stage, the oil / water emulsions formed in the previous phase break, causing coalescence between the oil droplets. For this, a malaxing tank made of stainless steel with horizontal and vertical rotors is used, in addition, an outer jacket with hot water between 45-50 ˚C is integrated. The dough is kneaded through blades that have different shapes, made of stainless steel, which rotate slowly (15-20 rpm). Malaxation is a key step in the balance between the quantity and quality of the extracted olive oil.

As the traditional pressing is concerned, Petrakis (2006) also explained that the traditional pressing technology consists of extracting the oil under pressure using hydraulic presses, its operated during 45-60 min, with gradually increasing of pressure up to 400atm, this value remains constant for 10-12 min. Subsequently, an amount of water is added to remove the solid material retained. Therefore, at the end of the process a pomace with moisture content of approximately 28% is obtained. In Figure 2.7 a description of it is presented.

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Figure 2.7: Traditional discontinuous pressing process.

 Continuous centrifugation process

The continuous process was developed as a solution to the need to produce olive oil in greater quantity and at a lower cost. With this objective, the hydraulic presses are replaced by a horizontal and two-phase centrifugal (decanter) system, which uses the centrifugal force to separate the liquid phase from the solid paste of olives. The initial part of the process is the same as the traditional method. The figure 2.8 shows the two types of continuous processes used for the olive oil production.

 Three- phases centrifugation

In the tree-phase centrifugation process, an amount of warm water is added, about 40-60% of the weight of the olives, in order to form a fluid paste that could facilitates the separation. Then, this diluted paste passes through a horizontal centrifuge. From this, three phases are obtained, consisting of an oily extract, vegetable water mixed with the added water (OMW) and pomace (45% moisture content). This process is more advantageous than the traditional one due to a higher quality of the oil. However, an important disadvantage is that since the water consumption is higher than the amount of waste water produced is about 1.25-1.75 times more compared to conventional technology (Petrakis, 2006). Additionally, this water in the initial wash removes a large portion of polyphenols. Therefore, it requires special treatment before being discarded.

 Two- phases centrifugation

On the other hand, the two-phases centrifugation process is similar to the tree-phases process, but differs in the amount of water used (lower in this case). It was created as an attempt to solve issues with the vegetation water waste treatment, because the amount of phenols in the water after washing is lower. A kind of sludge is obtained, also called

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"Olive wet cake", it is constituted by pomace with 60-75% of moisture and certain quantity of sugars as a result of the water recycle (Arjona, Garcia, & Ollero, 1999).

Figure 2.8: Continuous centrifugation processes.

Usually, the pomace obtained in the three different processes contains a certain amount of oil, which is economically convenient to recover. Whit this purpose, moisture content is reduced to at least 8% to obtain an efficient extraction (Mendez & Ruiz, 2006).

The reduction of moisture content in the olive pomace is done through a rotary dryer. This type of dryer is composed of a rotating cylinder supported on rolling strips. The speed of the rotation depends on the size of the cylinder, it can be simple or double step. In this process, drying gases at 400-800C are used, which can come, for example, from the burning of exhausted olive pomace derived after the recovery (Mendez & Ruiz, 2006).

Arjona R. (1999), explained that a high moisture contents (65% w/w) and a high amount of sugars present as consequent of the recirculation of the vegetable water, increase the tendency of the olive pomace to adhere to the walls of the drying cylinder. Specifically, at the entrance, hindering the flow of the hot gas stream and, consequently, increasing the risk of fire.

In the other hand, the chemical extraction phase is generally carried out in the following phases: first pulp is granulated, then the extraction with hexane is carried out and finally the desolventization of the pulp and distillation of the lean mixture is accomplished.

The final product is "Olive exhausted Pomace" and has a high combustion heat, which makes it attractive as biofuel.

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Table 2.2: Comparison of the three types of olive oil processes (Anon, 2000)

Input Output

Production process Description Quantity Description Quantity [kg]

Traditional pressing

process Olives 1000 kg Oil 200

Washing water 0.1–0.12 m3

Solid waste 25% water

6% oil

400

Energy 40–63 kWh Waste water

88% water 600

Three-phase decanter Olives 1000 kg Oil 200

Washing water 0.1–0.12 m3

Solid waste 50% water

4% oil

500–600

Fresh water for

decanter 0.5–1 m3

Waste water 94% water

1% oil

1,000–1,200

Water to polish

the impure oil 10 kg

Energy 90–117 kWh

Two-phase decanter Olives 1,000 kg Oil 200

Washing water 0.1–0.12 m3

Solid waste 60% water

3% oil

800–950

Energy < 90–117 kWh

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