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Supporting information to manuscript MATCHEMPHYS-D-14-00098

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Supporting information to manuscript MATCHEMPHYS-D-14-00098

1. S1:Measured percentages of C, O, H, Cu and N in the composites compared with the “hypothetical” ones, calculated combining the percentage of HNP90R and HKUST-1 in the composites with the percentages of the elements in HNP90R and HKUST-1.

0 10 20 30 40 50 60 70 80 90 100 0 20 40 60 80 100

C

%

w

t.

% HNP90R measured calculated 0 10 20 30 40 50 60 70 80 90 100 0 20 40 60 80 100

O

%

w

t.

% HNP90R measured calculated 0 0,5 1 1,5 2 2,5 3 3,5 4 4,5 5 0 20 40 60 80 100

H

%

w

t.

% HNP90R measured calculated 0 5 10 15 20 25 30 35 40 45 50 0 20 40 60 80 100

C

u

%

w

t.

% HNP90R measured calculated 0 1 2 3 4 5 6 7 8 9 10 0 20 40 60 80 100

N

%

w

t.

% HNP90R measured calculated

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2. TGA curves of the physical mixture of two components (HNP90R and HKUST-1) of the composites. 0 20 40 60 80 100 50 150 250 350 450 550 650 750

w

eig

h

t,

%

temperature, °C HKUST-1 MGL-2 (PM) MGL-4 (PM) HNP90R

Figure S2. TGA curves in oxidative environments of a physical mixture (PM) of two components (HNP90R and HKUST-1) built mixing at the appropriate % wt. the two pure components. HNP90R and HKUST-1 are also reported for comparison.

3. Elemental mapping using energy dispersive X-ray (EDX) analysis

HKUST-1

C

Cu

(3)

MGL-1 MGL-4

C

Cu

O

C

Cu

O

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