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TABLE OF CONTENTS Chapter 1 - Post- to late-Hercynian evolution in western central Europe

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TABLE OF CONTENTS

I

TABLE OF CONTENTS

Chapter 1 - Post- to late-Hercynian evolution in western central Europe

1.1 Introduction 1

1.2 Plate tectonic models 2

1.3 The Hercynian magmatism 7

1.4 Geochemical signatures of late- to post-collisional magmatism 13 1.4.1 Late- to post-collisional magmatism in the Calabria-Peloritani Orogen 15 1.4.2 Post-collisional magmatism in the Sicilian - Maghrebian chain 17

Chapter 2 - Geological background and field features

2.1 Introduction 19

2.2 The Calabria-Peloritani Orogen 19

2.2.1 The Serre Massif 21

2.2.2 Field features of Serre dykes 25

2.3 The Sicilian - Maghrebian Chain 29

2.3.1 Field features of Sicily dykes 34

Chapter 3 - Petrographic features

3.1 Serre dykes 37

3.1.1 “Mammola – Piani di Limina” dykes (PDL – LMA samples) 37

3.1.2 “Fosso foletti” dykes (F samples) 41

3.1.3 “Antonimina” dykes (A samples) 43

3.1.4 “Villaggio Zomaro” dykes (VZ samples) 45

3.1.5 “San Todaro” dykes (ST samples) 48

3.2 Sicilian dykes 50

3.2.1 “Leonforte” dyke (VG samples) 50

3.2.2 “Roccapalumba-Margana-Lercara” area dykes 52

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TABLE OF CONTENTS

II Chapter 4 - Mineral chemistry

4.1 Results 58 4.1.1 Pyroxene 58 4.1.2 Amphibole 62 4.1.3 Feldspar 64 4.1.4 Biotite 66 4.1.5 White mica 67 4.1.6 Accessory minerals 69

Chapter 5 - Whole-rock major and trace-element geochemistry

5.1 Introduction 70

5.2 Calabrian dykes 70

5.2.1 Tectono-magmatic discrimination of Calabria dykes 81

5.3 Sicilian dykes 84

5.3.1 Alkaline intrusion 87

5.3.2 Tholeiitic intrusions 92

5.3.3 Tectono-magmatic discrimination of the Sicilian dykes 93 Chapter 6 - Sr-Nd isotopic data

6.1 Introduction 94

6.2 Calabrian dykes 96

6.3 Sicilian dykes 98

Chapter 7 - Petrogenetic models

7.1 Calabrian dykes 101

7.1.1 Serre basaltic andesites 102

7.1.2 Serre andesites 105

7.1.3 Serre dacites-rhyodacites 108

7.2 Sicilian dykes 110

7.2.1 Magmatic sources 111

7.2.2 Role of crustal contamination 113

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TABLE OF CONTENTS

III

Conclusions 118

References 123

Appendices: 143

Appendix 1 - List of samples 144

Appendix 2 – Tables 149

Appendix 3 - Analytical methods 171

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