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H, C, N, O and S stable isotope ratios of livestock from Cameroon

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Emirates Journal of Food and Agriculture http://ejfa.info/

Abstracts of “ChimAlSi_2012” IX° Italian Congress of Food Chemistry. “Food, Functional Foods and Nutraceuticals” Hotel Continental Terme, Ischia (NA), Italy, June 03-07, 2012

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H, C, N, O and S stable isotope ratios of livestock from Cameroon

Matteo Perini1,2, Federica Camin1, Edi Piansentier2

1IASMA Edmund Mach Foundation, Via E. Mach 1, 38010 San Michele all’Adige (TN), Italy.2Department of Agricultural and Environmental Science, University of Udine, Via Sondrio 2A, 33100 Udine, Italy.

E-mail: matteo.perini@iasma.it

Abstract

70% of the population in Cameroon is economically dependent on agriculture, essentially represented by livestock production. There are around six million cattle in Cameroon, mostly belonging to the Zebu breed. In order to improve meat and milk productivity for the Gudali zebu breed in Cameroon, international cooperation between Italy and Cameroon has recently been started up. Within the context of this cooperation, 60 samples from three different cattle species (Gudali, White and Red Fulani) from different parts of Cameroon (the Sudano-Sahelian area in the North, Guinea high savannah in the East, high plateau in the West and forests in the South) were subjected to analysis of the 13C/12C, 15N/14N, 34S/32S, 2H/H and 18O/16O

ratios of defatted dry matter and the 13C/12C, 2H/H and 18O/16O ratios of fat, using IRMS after combustion or pyrolysis. Stable isotope ratios of bio-elements have already been shown to be capable of characterising meat products on the basis of animal diet and the geo-climatic characteristics of the area of provenance (Camin et al., 2007; Perini et al., 2009; Schmidt et al., 2011). Livestock from Cameroon are characterised by typical δ13C values, due to an animal diet based on C4 plants (such as Echinochloa or Panicum) and δ34S values.

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Evaluation of stylbenes content in grapes (cv. Uvalino) during ripening and drying

Federico Piano, Davide Pes, Eleonora Bertolone and Daniela Borsa

CRA ENO- Centro di Ricerca per l’Enologia, via P. Micca 35, 14100 Asti (AT), Italy E-mail: daniela.borsa@entecra.it

Abstract

The chemical compounds belonging to the stilbenes have recently received a particular attention due to the role they play in the plant’s physiology (phytoalexins) and for their anti-oxidant properties. The Uvalino is a red-berry grape variety typically grown in Piedmont, Italy. This cultivar is characterised by its ability to synthesise large amounts of resveratrol glucoside (trans piceid) [ref]. This explains its high resistance to Botrytis cinerea. The aim of the work is the evaluation of stylbenes and other phenolics during ripening and drying of Uvalino grapes. After accumulation, values for piceatannol and trans-pterostylbene remain constant during the whole ripening period, while the piceide isomers continue to be synthesized until vintage. At the harvest the most aboundant stylbene appears to be the piceide (trans and cis) and trans-pterostylbene, while

trans-piceatannol is the lowest. The amount of total stylbenes found is remarkably higher than in other Piedmontese, Italian

and international wines. Due to the high levels of resveratrol also in the Uvalino wines, the study of the different stylbenes found in grapes, both in their glucoside and free forms, could be interesting for nutraceutic purposes, or alternatively, be used as a varietal marker. The determination of the stylbenes during ripening, suggests that their synthesis begins at veraison, as for antocyanins, but the stylbenes accumulation in berries happens suddenly. The high content in stylbenes and the low quantity of antocyanins are a varietal character. The amount and the evolution of stylbenes and other phenolic compounds have been monitored during drying in a drying room and over-ripening on the plant.As expected, the berries drying process appears to be more intense in grapes placed in a drying room, while all compounds are reduced when drying takes place directly on the plant, irrespective of the calculation method.During grape dryng, stylbenes and flavonols show large percentual reductions, even though the formers are higher, both at vintage and after drying.When drying takes place under optimal temperature and humidity conditions, as in the drying room, the values of the main phenolics indices are higher than those found at vintage. On the other hand, on the plant, the reductions are far more important, with the exception of stylbenes and hydroxy-cynnamic acids.

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