Appendice B
111
A
A
p
p
p
p
e
e
n
n
d
d
i
i
c
c
e
e
B
B
–
–
C
C
h
h
e
e
m
m
k
k
i
i
n
n
m
m
e
e
c
c
h
h
a
a
n
n
i
i
s
s
m
m
ELEMENTS H O N END SPECIESH O2 OH O H2 H2O HO2 H2O2 N N2 NO HNO N2O END
THERMO END
REACTIONS KJOULE/MOLE !Units are cm3, mol, s, KJ and K
H+O2=OH+O 2.E+14 0.00 70.30 H2+O=OH+H 1.8E+10 1.00 36.93 H2O+O=OH+OH 5.9E+09 1.30 71.25 H2+OH=H2O+H 1.17E+09 1.30 15.17 H+O2+M=HO2+M 2.3E+18 -0.8 0.00 H2/1./ H2O/6.5/ O2/0.4/ N2/0.4/ H+HO2=OH+OH 1.5E+14 0.00 4.20 H+HO2=H2+O2 2.5E+13 0.00 2.93 OH+HO2=H2O+O2 2.E+13 0.00 4.18 H+H+M=H2+M 1.8E+18 -1.00 0.00 H2/1./ H2O/6.5/ O2/0.4/ N2/0.4/ H+OH+M=H2O+M 2.2E+22 -2.00 0.00 H2/1./ H2O/6.5/ O2/0.4/ N2/0.4/ HO2+HO2=H2O2+O2 2.E+12 0.00 0.00 H2O2+M=OH+OH+M 1.3E+17 0.00 190.38 H2O2+OH=H2O+HO2 1.E+13 0.00 7.53 O+HO2=OH+O2 2.E+13 0.00 0.00 H+HO2=O+H2O 5.E+12 0.00 5.90 H+O+M=OH+M 6.2E+16 -0.60 0.00 O+O+M=O2+M 6.17E+15 -0.50 0.00 H2O2+H=H2O+OH 1.E+13 0.00 15.02 H2O2+H=HO2+H2 4.79E+13 0.00 33.26 O+OH+M=HO2+M 1.E+16 0.00 0.00 H2+O2=OH+OH 1.7E+13 0.00 200.0 O+N2=N+NO 1.82E+14 0.00 319.02 O+NO=N+O2 3.8E+09 1.00 173.11 H+NO=N+OH 2.63E+14 0.00 210.94 NO+M=N+O+M 3.98E+20 -1.50 627.65 N2+M=N+N+M 3.72E+21 -1.60 941.19 N2O+O=NO+NO 6.92E+13 0.00 111.41 N2O+O=N2+O2 1.E+14 0.00 117.23 N2O+N=N2+NO 1.E+13 0.00 83.14 N+HO2=NO+OH 1.E+13 0.00 8.31 N2O+H=N2+OH 7.6E+13 0.00 63.19 HNO+O=NO+OH 5.01E+11 0.50 8.31 HNO+OH=NO+H2O 1.26E+12 0.50 8.31 NO+HO2=HNO+O2 2.E+11 0.00 8.31
