*52<.892:!+ -.032 (:;-2 -2 *-25.
$6::68+:6 -2 '2,.8,+ 25
).,563602. #1242,1. .- %5.80.:2,1.
:;;:8F B; G?FD6EBGA9 CD:(FD:6F@:AF
BA I6EF: 68F>H6F:9 E?G9<: 6A6:DB7>8
9><:EF>BA
9W\\) @RLQNTJ E>@BA:FF>
/8664;;487
Polc0 H^f DO NGUYEN '.<2.=.8
Polc0 Rl_boql RAGA '.<2.=.8
Polc0 Aibpp^kaol TROVARELLI './.8..
Polc0 Ai_fk PINTAR './.8..
Do0 Akqlkfkl S^is^qlob ARICO* './.8..
Arqelo*p b/j^fi< jf`ebi^0pfjlkbqqf@rkfra0fq
Arqelo*p ^aaobpp<
Dfm^oqfjbkql af Cefjf`^. Ffpf`^ b Aj_fbkqb
Ukfsbopfq'^ abdif Sqraf af Uafkb Vf^ abi Clqlkf#`fl. 32: 55322 Uafkb x Iq^if^ qbi0 -5; 2654 77::49 c^u0 -5; 2654 77::25
.DCH<CHG
4LRPMCSBRHML '
' <GDMPV *
303 Frka^jbkq^ip lc riqo^plrka qob^qjbkq 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 7 30303 Uiqo^plrka afpfkqbdo^qflk jb`e^kfpjp 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 7 30304 F^`qlop fk$rbk`fkd qeb `^sfq^qflk mebkljbk^ 0 0 0 0 0 0 0 0 0 0 0 0 8 30305 Uiqo^plrka dbkbo^qflk 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 : 30306 Pltbo ^ka bkbodv nr^kqf#`^qflk 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 33 30307 Es^ir^qflk lc riqo^plrka afpfkqbdo^qflk b%`fbk`v 0 0 0 0 0 0 0 0 0 0 34 304 Frka^jbkq^ip lc ^k^bol_f` afdbpqflk 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 39 30403 Ak^bol_f` afdbpqflk mol`bpp _^pf` qeblov 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 3: 30404 V^of^_ibp fk$rbk`fkd ^k^bol_f` afdbpqflk 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 3: 30405 BMP qbpq 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 45 30406 E"b`q lc riqo^plrka mobqob^qjbkq lk ^k^bol_f` afdbpqflk 0 0 0 0 0 0 48 305 Frka^jbkq^ip lc obpmfoljbqov 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 4; 30503 Ouvdbk rmq^hb o^qb +OUR, 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 4; 30504 Ci^ppf#`^qflk lc obpmfoljbqbop 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 4; 30505 Uiqo^plkf` qob^qjbkq ^ka ^k^bol_f` afdbpqflk qbpq mbocloj^k`b bs^i/
r^qflk _v obpmfoljbqof` qb`ekfnrbp 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 52
( 6@RDPH@JQ @LC 6DRGMCQ ))
403 S^jmib 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 55 404 Amm^o^qrp 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 57 40403 Uiqo^plkf` afpormqbo 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 57 40404 Sbq rm lc _^q`e ^k^bol_f` afdbpqflk pvpqbj 0 0 0 0 0 0 0 0 0 0 0 0 0 5; 40405 Sbq rm lc obpmfoljbqbo 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 62 405 P^o^jbqbop 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 66
40503 COD ^ka plir_ib COD/Mbqela 7442 D lc Sq^ka^oa
Mbqelap 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 66 40504 TOC/Mbqela 7532 B lc Sq^ka^oa Mbqelap/ ^ka TN 0 0 0 0 0 0 0 0 67 40505 UV476 A_plomqflk /Mbqela 7;32 B lc Sq^ka^oa Mbqelap 0 0 0 0 0 68 40506 Nfqoldbk. ^jjlkf^ /HACH `lilofjbqof` jbqela ^a^mqba colj Sq^k/
a^oa Mbqela 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 69 40507 Pelpmelorp /HACH `lilofjbqof` jbqela ^a^mqba colj Sq^ka^oa
Mbqela 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 69 40508 Tlq^i ^ka Vli^qfib Slifap /Mbqela 4762 B ^ka 4762 E lc Sq^ka^oa
Mbqelap 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 6: 40509 C^o_lk ^ka Nfqoldbk +lk aov _^pfp, 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 6:
@@ .DCH<CHG
4050: Bfld^p `ljmlpfqflk 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 6; 4050; Mf`olp`lmf` l_pbos^qflkp 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 6; 405032 P^oqf`ib pfwb ^k^ivpfp 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 6;
) :DQSJRQ @LC 0HQBSQQHML *'
503 Uiqo^plrka qob^qjbkq obpriqp 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 73 50303 Pevpf`^i bs^ir^qflk 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 73 50304 Cebjf`^i bs^ir^qflk 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 77 50305 Ffk^i `lkpfabo^qflkp 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 82 504 B^q`e ^k^bol_f` afdbpqflk obpriqp 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 84 50403 Ak^bol_f` afdbpqflk qbpqp ^q F1I > 207 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 84 50404 Ak^bol_f` afdbpqflk qbpqp ^q F1I > 3 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 86 50405 Cljm^ofplk _bqtbbk af"bobkq F1I o^qfl 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 89 50406 Ekbodv `lkpfabo^qflkp 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 8; 50407 Ffk^i `lkpfabo^qflkp 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 92 505 Rbpmfoljbqof` qbpq obpriqp 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 92 50503 SOUR qbpq obpriqp 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 92 50504 Ffk^i `lkpfabo^qflkp 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 95 /MLBJSQHMLQ +* .HAJHMFP@NGV +,
2@GH D= 0@>IF<G
303 Dbsbilmjbkq ^ka `lii^mpb lc ^ _r__ib 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 8 304 C^sfq^qflk^i jf`ol_r__ib 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 8 305 Tvmbp lc elokp rpba fk riqo^plkf` qob^qjbkq 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 32 306 Teb clro pqbmp lc ^k^bol_f` afdbpqflk mol`bpp< 30 Hvaolivpfp 40 A`faldbk/
bpfp 50 A`bqldbkbpfp 60 Mbqe^kldbkbpfp 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 3; 307 Rbdobppflk jlabip clrka _v S`efbs^kl bq ^i0 [86] 0 0 0 0 0 0 0 0 0 0 0 0 0 0 54 308 Rbdobppflk jlabip clrka _v S`efbs^kl bq ^i0 [32] 0 0 0 0 0 0 0 0 0 0 0 0 0 0 54 403 Pelqldo^me lc UIP472 `bii afpormqbo +Do0Hfbip`ebo, 0 0 0 0 0 0 0 0 0 0 0 0 0 58 404 S`ebjb lc UIP472 `bii afpormqbo +Do0 Hfbip`ebo, 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 59 405 C^if_o^qflk tfqe KI plirqflk 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 59 406 Pelqldo^me lc _^q`e ^k^bol_f` afdbpqbop 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 62 407 S`ebjb lc _^q`e ^k^bol_f` afdbpqbop 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 63 408 Pelqldo^me lc obpmfoljbqbo 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 64 409 S`ebjb lc obpmfoljbqbo 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 65 503 Ij^dbp lc rkqob^qba ^ka plkf`^qba WAS3. 347u 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 74 504 Ij^dbp lc rkqob^qba ^ka plkf`^qba WAS4. 347u 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 75 505 WAS3 m^oqf`ib pfwb afpqof_rqflk 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 76 506 WAS4 m^oqf`ib pfwb afpqof_rqflk 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 76 507 E"b`q lc pmb`f#` bkbodv fkmrq lk pCOD 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 78 508 E"b`q lc pmb`f#` bkbodv fkmrq lk DOC `lk`bkqo^qflkp 0 0 0 0 0 0 0 0 0 0 0 78 509 Cloobi^qflk _bqtbbk DOC ^ka UV476 clo WAS3 p^jmibp +^q af"bobkq
pmb`f#` bkbodv fkmrqp, 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 7; 50: Cloobi^qflk _bqtbbk DOC ^ka UV476 clo WAS4 p^jmibp +^q af"bobkq
pmb`f#` bkbodv fkmrqp, 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 7; 50; E"b`q lc pmb`f#` bkbodv fkmrq lk ^jjlkf^ kfqoldbk `lk`bkqo^qflkp 0 0 0 82 5032 E"b`q lc pmb`f#` bkbodv fkmrq lk plir_ib kfqoldbk `lk`bkqo^qflkp 0 0 0 0 0 82 5033 Crjri^qfsb _fld^p molar`qflk lc rkqob^qba ^ka qob^qba WAS3 ^q F1I>207 85 5034 Crjri^qfsb _fld^p molar`qflk lc rkqob^qba ^ka qob^qba WAS4 ^q F1I>207 86 5035 mH s^of^qflkp arofkd _^q`e ^k^bol_f` qbpqp ^q F1I>207 0 0 0 0 0 0 0 0 0 0 0 87 5036 Crjri^qfsb _fld^p molar`qflk lc rkqob^qba ^ka qob^qba WAS4 ^q F1I>3 0 87 5037 Crjri^qfsb _fld^p molar`qflk lc rkqob^qba ^ka qob^qba WAS3 ^q F1I>3 0 88 5038 mH s^of^qflkp arofkd _^q`e ^k^bol_f` qbpqp ^q F1I>3 0 0 0 0 0 0 0 0 0 0 0 0 89 5039 Crjri^qfsb _fld^p molar`qflk lc WAS4 ^q af"bobkq F1I 0 0 0 0 0 0 0 0 0 0 8: 503: Crjri^qfsb _fld^p molar`qflk lc WAS3 ^q af"bobkq F1I 0 0 0 0 0 0 0 0 0 0 8: 503; Ekbodv _^i^k`b 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 8; 5042 OD s^irbp sboprp qfjb +rkqob^qba WAS4, 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 93 5043 SOUR qbpq lc rkqob^qba ^ka qob^qba WAS3 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 93
@J 2@GH D= 0@>IF<G
2@GH D= 689A<G
303 F^`qlop fk$rbk`fkd qeb `^sfq^qflk mebkljbk^ 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 9 304 Eumobppflkp ql nr^kqfcv piradb afpfkqbdo^qflk 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 34 305 Bfld^p `ljmlpfqflk 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 43 306 Ak^bol_f` afdbpqflk qbpqp< `lkafqflkp ^ka obpriqp 0 0 0 0 0 0 0 0 0 0 0 0 0 0 4: 403 Pevpf`^i/`ebjf`^i `e^o^`qbofw^qflk lc rkqob^qba p^jmibp +`lkqoli, 0 0 0 0 0 56 404 Ce^o^`qbofpqf`p lc riqo^plkf` UIP472 `bii afpormqbo +Do0 Hfbip`ebo, 0 0 0 0 57 405 P^o^jbqbop clo riqo^plrka qob^qjbkq bs^ir^qflk 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 5: 406 P^o^jbqbop clo ^k^bol_f` afdbpqflk mbocloj^k`b bs^ir^qflk 0 0 0 0 0 0 0 0 0 64 503 Crq af^jbqbo lc WAS3 ^ka WAS4 ^q af"bobkq pmb`f#` bkbodv fkmrq fk`ob^pbp 77 504 pCOD `lk`bkqo^qflk lc WAS3 ^ka WAS4 ^q af"bobkq pmb`f#` bkbodv fkmrqp 79 505 DOC `lk`bkqo^qflk lc WAS3 ^ka WAS4 ^q af"bobkq pmb`f#` bkbodv fkmrqp 79 506 UV476 ifdeq ^_plomqflk `lk`bkqo^qflkp lc WAS3 ^ka WAS4 ^q af"bobkq
pmb`f#` bkbodv fkmrqp 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 7: 507 Ajjlkf^ kfqoldbk `lk`bkqo^qflk lc WAS3 ^ka WAS4 ^q af"bobkq pmb`f#`
bkbodv fkmrqp 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 83 508 Slir_ib kfqoldbk `lk`bkqo^qflk lc WAS3 ^ka WAS4 ^q af"bobkq pmb`f#`
bkbodv fkmrqp 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 83 509 Ak^bol_f` afdbpqflk obpriqp ^q F1I>207 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 85 50: Ak^bol_f` afdbpqflk obpriqp ^q F1I>3 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 88 50; SOUR s^irb clo rkqob^qba ^ka qob^qba piradbp 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 95 5032 OD42 s^irbp clo rkqob^qba ^ka qob^qba piradbp 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 95 5033 Pobaf`qfkd ^ka bumbofjbkq^i pmb`f#` _fld^p molar`qflk +lk TS _^pfp, 0 0 0 96
1CHFD;I:H@DC
Drb ql qeb dob^q ro_^k ^ka fkarpqof^i absbilmjbkq. i^odb ^jlrkqp lc t^pqb ^`qfs^qba piradb +WAS, ^ob molar`ba fk jrkf`fm^i ^ka fkarpqof^i t^pqbt^qbo qob^qjbkq mi^kqp +WWTPp,0 Siradb afpmlp^i fp _b`ljb lkb lc qeb jlpq `or`f^i ^pmb`q lc ^ WWTP j^k/ ^dbjbkq0 Blqe b`lkljf`^i ^ka bksfolkjbkq^i `lkpqo^fkqp jrpq _b q^hbk fkql ^``lrkq0 Um ql 87) lc qeb lmbo^qfkd `lpqp lc ^ WWTP +fk`irafkd bkbodv. j^k bjmilvjbkq ^ka loafk^ov j^k^dbjbkq, fp arb ql piradb qob^qjbkq. e^kaifkd ^ka afpmlp^i [3]0 Ok qeb lqebo e^ka. i^tp t^kq ql do^ar^iiv _^k qeb qo^afqflk^i afpmlp^i jbqelap +b0d0. i^ka#ii, _v moljlqfkd kbt jbqelap tfqe ^ dob^qbo bksfolkjbkq^i prpq^fk^_fifqv +3;;;1531EC,0 Mloblsbo. tfqe fk`ob^pfkd fk dil_^i t^ojfkd ^ka `ifj^qb `e^kdb. qeb dobbkelrpb d^pbp +GHGp, bjfppflkp colj qeb t^pqb pb`qlo ^ob lc fk`ob^pfkd `lk`bok0 Iq^iv. pr_p`of_fkd ql qeb Kvlql Polql`li. fp `ljjfqqba ql obar`b dobbkelrpb d^pbp= obkbt^_ib bkbodfbp mi^v ^k fjmloq^kq olib fk qefp mol`bpp ^ka fk m^oqf`ri^o _flj^ppbp `lria `lkqof_rqb fk ^ pfdkf#`^kq t^v _b`^rpb qebv ^ob ^ \`^o_lk kbrqo^i( crbip0 Ik 4228. qeb UE moljlqba ^k ^`qflk mi^k +IP12813656, fk tef`e ^ii Erolmb^k jbj_bo pq^qbp rkaboqllh ql ^`efbsb pfjriq^kblrpiv qeobb l_gb`qfsbp fk 4242<
& 42) obar`qflk lc dobbkelrpb d^p bjfppflkp= & 42) bkbodv colj obkbt^_ib plro`bp= & 42) fjmolsbjbkq fk bkbodv b%`fbk`v0
Tebobclob. b"loqp jrpq _b alkb ql jfkfjfwb WAS molar`qflk ^ka fk`ob^pb qeb b%/ `fbk`v lc piradb qob^qjbkq qb`eklildv0 Teb dbkbo^qflk lc s^irb/^aaba molar`qp +pr`e ^p efde nr^ifqv _flplifap clo i^ka ^mmif`^qflk ^ka _fld^p, colj WAS `^k _b ^k b"b`qfsbkbpp pqo^qbdv clo prpq^fk^_ib piradb j^k^dbjbkq0
Bflildf`^i mol`bppbp pr`e ^p ^bol_f` ^ka ^k^bol_f` afdbpqflk ^ob tfabiv rpba clo WAS pq^_fifw^qflk0 Teb ^fj lc qebpb mol`bppbp fp ql obar`b qeb piradb afpmlp^i ^ka. ^q qeb p^jb qfjb. molar`b efde nr^ifqv _flplifap ^ka dbkbo^qb obkbt^_ib bkbodv +b0d0. _fld^p arofkd ^k^bol_f` afdbpqflk,0
Sfk`b ^bol_f` afdbpqflk fp klq b`lkljf`^iiv sf^_ib ql qob^q i^odb ^jlrkq lc piradb _b`^rpb lc efde bkbodv `lkprjmqflk lc ^bo^qflk pvpqbj. ^k^bol_f` afdbpqflk fp qeb jlpq ^mmifba mol`bpp fk jbafrj ^ka i^odb WWTPp0
Gbkbo^iiv ^k^bol_f` afdbpqbop ^ob cba tfqe ^ jfuqrob lc mofj^ov ^ka pb`lka^ov +t^pqb ^`qfs^qba, piradb0 Ce^o^`qbofpqf`p lc mofj^ov ^ka t^pqb ^`qfs^qba piradb ^ob af"bobkq0 WAS fp of`ebo fk krqofbkqp ^ka mllobo fk `lkq^jfk^kqp ^p eb^sv jbq^ip ^ka lod^kf` jf`olmliirq^kqp qe^k mofj^ov lkb [4]0 Mloblsbo. WAS fp jlob afirfqba ^ka fq fp jlob af%`riq ql afdbpq qe^k mofj^ov piradb [5]0 Tebobclob. qeb ^k^bol_f` pq^_fifw^qflk fp ^ pilt mol`bpp `e^o^`qbofwba _v ilkd obpfabk`b qfjbp ^ka i^odb afdbpqbo slirjbp0
$ 1CHFD;I:H@DC
Drofkd ^k^bol_f` afdbpqflk. abdo^a^_ib lod^kf` `ljmlrkap ^ob `lksboqba fkql jbqe^kb +CH(, ^ka `^o_lk aflufab +CO&, fk qeb ^_pbk`b lc bibjbkq^i luvdbk tfqe ^ pbofbp lc jf/
`ol_flildf`^i mol`bppbp0 Teb `lksbopflk m^qet^v lc qeb pr_pqo^qb ql _fld^p `^k _b afsfaba fkql clro pqbmp< evaolivpfp. ^`faldbkbpfp. ^`bqldbkbpfp ^ka jbqe^kldbkbpfp0 Teb jbqe^kl/ dbkbpfp fp kloj^iiv qeb ifjfqfkd pqbm _rq. fc qeb pr_pqo^qbp ^ob m^oqf`ri^qb pr`e ^p pbt^db piradbp. qeb evaolivpfp fp qeb `lkqoliifkd pqbm [6]0
Ik loabo ql bke^k`b _flabdo^a^_fifqv lc lod^kf` plifap ^ka fjmolsb qeb pr_pbnrbkq ^k^bol_f` afdbpqflk. pljb mevpf`^i. `ebjf`^i ^ka qeboj^i mobqob^qjbkqp `^k _b ^mmifba ql WAS0 Ce^kdbp fk bfqebo hfkbqf` abdo^a^qflk o^qb lo abdo^a^_fifqv tfii bke^k`b _fld^p molar`qflk ^ka ^k^bol_f` afdbpqbo mbocloj^k`b [7]0 Ijmolsfkd o^qb `^k ^ipl ^iilt mol/ `bpp fkqbkpf#`^qflk< qeb evaolivpfp ob^`qflkp ^ob ^``bibo^qba tfqe ^ obar`qflk fk evao^rif` obqbkqflk qfjb ^ka `lkpbnrbkqiv fk afdbpqbo slirjb0 Ik ifqbo^qrob qebob ^ob ^iob^av bk/ `lro^dfkd obpriqp ql fjmolsb qeb mbocloj^k`b lc qeb afdbpqbo _v mob/qob^qfkd p^jmibp tfqe riqo^plkf` qob^qjbkq [8]. [9]. [:]0
Uiqo^plkf` qob^qjbkq fp rpba ql bke^k`b WAS $l` ab^ddiljbo^qflk ^ka jf`ol_f^i `bii t^ii _ob^h/rm [;]0 Ap obpriq lc riqo^plrka qob^qjbkq ^mmif`^qflk. qeb fkqo^`biiri^o j^qqbo fp obib^pba fkql ^nrblrp me^pb ^ka _b`ljbp ^s^fi^_ib clo pr_pbnrbkq abdo^a^qflk ql CH(
^ka CO& fk ^k^bol_f` afdbpqflk mol`bpp0 E%`fbk`v lc riqo^plrka qob^qjbkq abmbkap lk
pbsbo^i m^o^jbqbop pr`e ^p pmb`f#` bkbodv fkmrq. riqo^plkf` abkpfqv. TS `lkqbkq0
Osbo qeb i^pq vb^op. j^kv ^rqelop e^sb bs^ir^qba qeb piradb afpfkqbdo^qflk ^ka qeb _fld^p molar`qflk fk`ob^pb arb ql riqo^plrkap rpfkd mevpf`^i. `ebjf`^i ^ka _flildf`^i m^o^jbqbop0 Teb riqo^plrka qob^qjbkq e^p _bbk bpmb`f^iiv ^mmifba ql jrkf`fm^i t^pqb ^`qfs^qba piradbp0 Ik ifqbo^qrob qebob fp ^ i^`h lc fkcloj^qflkp ^_lrq qeb ^mmif`^qflk lc riqo^plrka qob^qjbkq lk fkarpqof^i t^pqb ^`qfs^qba piradbp0
Okb lc qeb fkkls^qfsb fab^p lc qefp tloh t^p ql ^mmiv riqo^plrka qob^qjbkq ql _lqe jrkf`fm^i ^ka fkarpqof^i t^pqb ^`qfs^qba piradbp0
Acqbo e^sfkd bs^ir^qba qeb b%`fbk`v lc riqo^plrkap afpfkqbdo^qflk qeolrde mevpf`^i ^ka `ebjf`^i m^o^jbqbop. ^klqebo ^fj lc qefp obpb^o`e tloh t^p ql bs^ir^qb qeb mlqbk/ qf^ifqfbp lc riqo^plrkap lk ^k^bol_f` afdbpqflk fjmolsbjbkq0
Ak fjmloq^kq m^o^jbqbo ql bs^ir^qb ^k^bol_f` afdbpqflk mbocloj^k`bp fp cbba1fkl`rirj +F1I, o^qfl. tef`e obmobpbkqp qeb o^qfl lc pr_pqo^qb ^jlrkq ql fkl`rirj ^jlrkq ^aaba ql ^k^bol_f` afdbpqbo0 Teb b"b`q lc F1I o^qfl lk ^k^bol_f` afdbpqflk lc plkf`^qba piradb e^p _bbk ifqqib fksbpqfd^qba fk ifqbo^qrob0 Tebobclob. fk loabo ql _bqqbo rkabopq^ka qeb fk$rbk`b lc riqo^plrka qob^qjbkq ^ka cbba1fkl`rirj o^qflp lk qeb piradb ^k^bol_f` ^`/ qfsfqv. _^q`e ^k^bol_f` _flabdo^a^_fifqv qbpqp +BMP qbpqp, tbob `^oofba lrq ^q af"bobkq cbba1fkl`rirj o^qflp0
Sfk`b ^ _flildf`^i lufa^qflk _bqqbo afp`ofjfk^qbp _bqtbbk abdo^a^_ib ^ka klk/abdo^a^_ib lod^kf` j^qqbo qe^k ^ pqolkd `ebjf`^i lufa^qflk. qeb b"b`qp lc riqo^plrka qob^qjbkq e^p _bbk ^ipl bs^ir^qba qeolrde _flildf`^i m^o^jbqbop0 Tebobclob. ^ obpmfoljbqof` mol`barob e^p _bbk fkqolar`ba ql bpqfj^qb _flildf`^i m^o^jbqbop ^p tbii ^p ql mobaf`q qeb _fld^p molar`qflk0 Teb ^fj t^p ql `loobi^qb qeb luvdbk abj^ka clo qeb #opq 42 elro lc qeb qbpq +OD42, ^ka sli^qfib plifap ql BMP qeolrde ^k ^mmolmof^qb obdobppflk jlabi molmlpba _v S`efbs^kl bq ^i0 [32]0 Teb obdobppflk jlabi t^p sbof#ba _v S`efbs^kl lk af"bobkq qvmbp lc lod^kf` ebqboldbkblrp _flj^ppbp. fk`irafkd pbt^db piradbp0
%
Teb lofdfk^ifqv lc qefp tloh t^p ql ^mmiv qeb S`efbs^kl*p jlabi ql _lqe plkf`^qba piradbp ^ka sbofcv fqp ^_fifqv lc mobaf`qflk tfqe ^ `ljm^ofplk _bqtbbk qeb `^i`ri^qba _fld^p molar`qflk ^ka qeb bumbofjbkq^i _fld^p molar`qflk. l_q^fkba _v qo^afqflk^i _^q`e ^k^bol_f` qbpqp0
Ik sfbt lc qebpb `lkpfabo^qflkp. qeb obpb^o`e tloh fp afsfaba fkql qeobb pqbmp< 4L RGD !PQR QRDN qeb b"b`q lc 42 hHw riqo^plrka qob^qjbkq lk $l` afpfkqbdo^qflk ^ka
`bii ivpfp e^p _bbk bs^ir^qba fk loabo ql rkabopq^ka qeb mlqbkqf^ifqv lc qefp mob/ qob^qjbkq lk WAS abdo^a^_fifqv0 A t^pqb ^`qfs^qba piradb +WAS3, q^hbk colj ^ mrim ^ka m^mbo WWTP ^ka ^ jrkf`fm^i t^pqb ^`qfs^qba piradb +WAS4, tbob plkf`^qba ^q af"bobkq pmb`f#` bkbodv fkmrqp ^ka qeb b"b`qp lk _lqe piradbp tbob `ljm^oba _v rpfkd mevpf`^i +pr`e ^p jf`olp`lmf` l_pbos^qflk ^ka m^oqf`ib pfwb afp/ qof_rqflk, ^ka `ebjf`^i +pr`e ^p plir_ib COD. afpplisba lod^kf` `^o_lk DOC. UV476. plir_ib kfqoldbk SN ^ka kfqoldbk ^jjlkf^ NH'/N, m^o^jbqbop0
4L RGD QDBMLC QRDN qtl _^q`e ^k^bol_f` afdbpqbop tbob pbq rm ql qbpq WAS ^k^bol_f` _flabdo^a^_fifqv0 Ak^bol_f` _flabdo^a^_fifqv qbpqp tbob mboclojba ^q F1I o^qfl bnr^i ql 207 ^ka 3 lk _lqe piradbp0 Vli^qfib plifap +VS, abdo^a^qflk. `rjri^qfsb ^ka pmb`f#` _fld^p molar`qflk tbob rpba ql l_pbosb qeb _^q`e ^k^bol_f` ob^`qlo mbocloj^k`bp0
4L RGD RGHPC QRDN ^ obpmfoljbqbo t^p pbq rm ql abqbojfkb _flildf`^i m^o^jbqbop pr`e ^p luvdbk rmq^hb o^qb +OUR,. pmb`f#` luvdbk rmq^hb o^qb +SOUR, ^ka luvdbk abj^ka clo qeb #opq 42 elro lc qeb qbpq +OD42, clo _lqe piradbp +plkf`^qba ^ka rkqob^qba,0 Bflildf`^i m^o^jbqbop tbob rpba ql bs^ir^qba piradb nr^ifqv ^ka piradb afpfkqbdo^qflk fkpqb^a lc COD m^o^jbqbo0 Aq qeb p^jb qfjb. qeb OD42 ^ka VS m^o^jbqbop tbob abqbojfkba ql mobaf`q qeb _fld^p molar`qflk tfqe ^ obdobppflk jlabi molmlpba _v S`efbs^kl bq ^i0 [32] fkpqb^a lc qeb qo^afqflk^i _^q`e ^k^bol_f` _flabdo^a^_fifqv qbpqp0
!
6?<DFK
,),
;]VMJUNV\JT[ WO ]T\ZJ[W]VM \ZNJ\UNV\
,),),
GT\ZJ[W]VM MR[RV\NPZJ\RWV UNLQJVR[U[
Teb riqo^plrka fp ^ `v`if` plrka mobpprob ^q cobnrbk`fbp ^_lsb 42 hHw0 Dbmbkafkd lk qeb cobnrbk`v. fq `^k _b afsfaba fkql qeobb obdflkp< mltbo riqo^plrka +42/322 hHw,. efde cobnrbk`v riqo^plrka +322 hHw/3 MHw, ^ka af^dklpqf` riqo^plrka +3/722 MHw,0 Webk qeb riqo^plrka t^sb molm^d^qbp fk ^ jbafrj. fq dbkbo^qbp ^ m^qqbok lc `ljmobppflkp ^ka o^obc^`qflkp0 Teb `ljmobppflk ^ka o^obc^`qflk `v`ibp molar`b ^ mlpfqfsb ^ka ^ kbd^qfsb mobpprob lk qeb ifnrfa. obpmb`qfsbiv0
Ap ^ obpriq lc obar`ba mobpprob. jf`ol_r__ibp ^ob clojba fk qeb o^obc^`qflk obdflkp0 Teb jf`ol_r__ibp. `lkq^fkfkd s^mlofwba ifnrfa ^ka d^p. lp`fii^qb rkabo qeb fk$rbk`b lc mlpfqfsb mobpprob ^ka bum^ka ql rkpq^_ib pfwb _bclob sflibkqiv `lii^mpfkd0 Ll`^ifwba qbjmbo^qrobp lc 7222 K ^ka mobpprobp lc 3:2 MP^ `^k _b ob^`eba [33]0 Tefp mol`bpp fp hkltk ^p `^sfq^qflk0 C^sfq^qflk e^p _bbk qo^afqflk^iiv `i^ppf#ba ^p lkb lc qtl qvmbp< qo^kpfbkq ^ka pq^_ib0 To^kpfbkq `^sfq^qflk fkslisbp i^odb/p`^ib s^of^qflkp fk qeb _r__ib pfwb +obi^qfsb ql fqp bnrfif_ofrj pfwb, lsbo ^ qfjb p`^ib lc ^ cbt ^`lrpqf` `v`ibp0 Tefp o^mfa doltqe rpr^iiv qbojfk^qbp fk ^ `lii^mpb lc s^ovfkd abdobbp lc sflibk`b0 Ok qeb lqebo e^ka. pq^_ib `^sfq^qflk rpr^iiv fkslisbp pj^ii/^jmifqrab +`ljm^oba ql qeb _r__ib o^afrp, lp`fii^qflkp ^_lrq ^k bnrfif_ofrj o^afrp0 Sq^_ib `^sfq^qflk fk jlpq fkpq^k`bp obpriqp fk ifqqib ^mmob`f^_ib _r__ib doltqe lsbo ^ qfjb p`^ib lc qelrp^kap lc ^`lrpqf` `v`ibp0 Sq^_ib `^sfq^qflk `^k ib^a ql qo^kpfbkq `^sfq^qflk ^ka qeb `lii^mpb lc ^ qo^kpfbkq `^sfqv `^k molar`b pj^iibo _r__ibp qe^q rkabodl pq^_ib `^sfq^qflk [34]0
Teb jfkfjrj ^jlrkq lc bkbodv obnrfoba ql fkfqf^qb `^sfq^qflk fp obcbooba ql ^p qeb `^sfq^qflk qeobpelia ^ka fq s^ofbp clo af"bobkq $rfap0 Okiv qeb bkbodv ^mmifba ^_lsb qeb qeobpelia tfii `lkqof_rqb ql qeb cloj^qflk lc ^ `^sfq^qflk _r__ib0 Ik t^qbo. `^sfq^qflk tfii dbkbo^iiv l``ro lk`b qeb riqo^plkf` bkbodv ofpbp ^_lsb 3 W1`j' ibsbip [35]0
A obmobpbkq^qflk lc qeb absbilmjbkq ^ka `lii^mpb lc ^ jf`ol_r__ib fp peltk fk Ffdrob 3030 Teb pqor`qrob lc ^ jf`ol_r__ib fp obmobpbkqba fk Ffdrob 3040
Teb `lii^mpfkd lc ^ erdb krj_bo lc jf`ol_r__ibp dbkbo^qbp efde efaol/jb`e^kf`^i peb^o clo`bp fk qeb ifnrfa proolrkafkd qeb _r__ibp [36]0 Ik ^aafqflk. qeb efde qbjmbo^/ qrob. molar`ba arofkd jf`ol_r__ib fjmilpflk. ab`ljmlpbp t^qbo fkql buqobjbiv ob^`qfsb
( #! 6?<DFK
Ffdrob 303< Dbsbilmjbkq ^ka `lii^mpb lc ^ _r__ib
evaoldbk ^qljp ^ka evaoluvi o^af`^ip +%OH, ^ka fk qeb `llifkd me^pb qebpb o^af`^ip tfii
ob`lj_fkb ql cloj evaoldbk mbolufab ^ka jlib`ri^o evaoldbk0
Bbqqbo piradb afpfkqbdo^qflk l``rop ^q 42/62 hHw cobnrbk`fbp [8]0 W^kd bq ^i0 [37] l_/ pbosba qe^q ^q ilt cobnrbk`fbp qeb `lkqof_rqflk lc lufafwfkd o^af`^ip lk piradb afpfkqbdo^/ qflk fp kbdifdf_ib0 Tebobclob. qeb piradb afpfkqbdo^qflk fp j^fkiv arb ql evaol/jb`e^kf`^i peb^o clo`bp0 Teb il`^ifwba efde qbjmbo^qrob ^ipl `lria ^ppfpq fk piradb afpfkqbdo^qflk0
Ffdrob 304< C^sfq^qflk^i jf`ol_r__ib
,),)-
;JL\WZ[ RV#]NVLRVP \QN LJ^R\J\RWV XQNVWUNVJ
#!#! 0IC;8B<CH8AG D= IAHF8GDIC; HF<8HB<CH )
T^_ib 303< F^`qlop fk$rbk`fkd qeb `^sfq^qflk mebkljbk^
2@BRMP <VND ME HL"SDLBD :DEDPDLBD
Fobnrbk`v Teb o^obc^`qflk me^pb fp peloqbkba _v fk`ob^pfkd qeb Vfpp`ebo bq ^i0 foo^af^qflk cobnrbk`v0 Tl j^fkq^fk ^k bnrfs^ibkq ^jlrkq +3;;:, [38] lc `^sfq^qflk^i bkbodv fkql qeb pvpqbj. qeb mltbo
pelria _b fk`ob^pba0 Terp. ^q efdebo cobnrbk`v jlob mltbo fp obnrfoba ql j^fkq^fk p^jb `^sfq^qflk^i b"b`q0
Slisbkq Teb cloj^qflk ^ka qeb pr_pbnrbkqiv `lii^mpb lc qeb C^pqol bq ^i0 sfp`lpfqv jf`ol_r__ibp dbkbo^qb peb^o clo`bp fkql qeb pvpqbj0 +4229, [39]
Sfk`b sfp`lpfqv fp ^ jb^prob lc ^ obpfpq^k`b.
qeb molar`qflk lc `^sfq^qflk b"b`qp fp jlob af%`riq fk ^ ifnrfa `e^o^`qbofwba _v efde sfp`lpfqv0
Slisbkq Teb plisbkq sfp`lpfqv ^ka proc^`b qbkpflk fk`ob^pb Teljmplk bq ^i0 proc^`b obar`b qeb o^qb lc jf`ol_r__ib cloj^qflk +3;;;, [3:] qbkpflk _rq fjmolsb qeb fkqbkpfqv lc _r__ib `lii^mpb0
Teb ^aafqflk lc proc^`q^kqp obar`bp qeb plisbkq proc^`b qbkpflk ^ka c^`fifqfbp _r__ib kr`ib^qflk0
Slisbkq Ic qeb s^mlro mobpprob lc qeb ifnrfa fp ilt. qebk C^pqol bq ^i0 s^mlro fq fp af%`riq ql fkar`b `^sfq^qflk fk qeb ifnrfa0 +4229, [39] mobppflk
G^p ^ka Teb mobpbk`b lc d^p1^fo fkql qeb ifnrfa pvpqbj M^plk bq ^i0 m^oqf`ri^qb `lria obar`b qeb fkqbkpfqv lc qeb obib^pba pel`h t^sb0 +4224, [3;] j^qqbo P^oqf`ri^qb j^qqbop. bpmb`f^iiv ifhb
qo^mmba s^mlro d^p kr`ibf fk qebfo `obsf`bp ^ka ob`bppbp. tfii obar`b qeb `^sfq^qflk b"b`q0
Euqbok^i Teb fk`ob^pfkd lc buqbok^i mobpprob o^fpbp Teljmplk bq ^i0 mobpprob qeb o^obc^`qflk mobpprob. tef`e fk`ob^pbp +3;;;, [3:]
qeb `^sfq^qflk `lii^mpb fkqbkpfqv0
Tbjmbo^qrob Teb `^sfq^qflk qeobpelia fk`ob^pbp tfqe ab`ob^pb Mlelih^o bq ^i0 fk qbjmbo^qrob lc _rih plirqflk0 Webk qeb plisbkq +3;;8, [42] ob^`ebp qeb plisbkq _lfifkd mlfkq. ^ i^odbo krj_bo
lc `^sfq^qflk _r__ibp ^ob molar`ba0 Tebv ^`q ^p ^ _^oofbo ql qeb plrka qo^kpjfppflk ^ka kriifcv qeb `^sfq^qflk b"b`qp0
Ikqbkpfqv Ik`ob^pfkd qeb plkf`^qflk fkqbkpfqv fk`ob^pbp qeb Lbfdeqlk T0G0 plkf`^qflk b"b`qp0 Iq fp afob`qiv molmloqflk^i +3;;7, [43] ql qeb pnr^ob ollq lc qeb ^jmifqrab lc qeb ^`lrpqf`
t^sb afsfaba _v qeb abkpfqv lc qeb ifnrfa ^ka qeb pmbba lc plrka fk qeb ifnrfa0
Aqqbkr^qflk Teb fkqbkpfqv lc qeb riqo^plrka fp ^qqbkr^qba ^p fq moldobpp qeolrde qeb jbafrj0
Teb ^qqbkr^qflk fp fksbopbiv molmloqflk^i ql qeb cobnrbk`v lc qeb riqo^plrka0 Hfde mltbo ^ka cobnrbk`v ^ob obnrfoba ql e^sb qeb p^jb fkqbkpfqv
* #! 6?<DFK
,),).
GT\ZJ[W]VM PNVNZJ\RWV
Teb jlpq tfabiv absf`bp rpba ql molar`b riqo^plkf` foo^af^qflk ^ob qeb \riqo^plkf` `ib^k/ fkd _^qep( ^ka qeb \mol_b pvpqbjp(0 Teb i^qqbo lkbp ^ob `e^o^`qbofwba _v ^ dob^qbo plkf`^qflk mltbo +rm ql 322 qfjbp dob^qbo, qe^k qeb #opq lkbp0 Ik ^kv `^pb. _lqe pvp/ qbjp ^ob ifjfqba _b`^rpb qebv lmbo^qb ^q ^ #uba cobnrbk`v abmbkafkd lk qeb qo^kpar`bo0 Gbkbo^iiv. qeb lmbo^qfkd cobnrbk`v fp 42 hHw ^ka 62 hHw clo mol_b ^ka `ib^kfkd _^qe pvpqbjp. obpmb`qfsbiv0 Sbm^o^qb q^filoba pvpqbjp jrpq _b pbq rm ql `^oov lrq qbpqp ^q af"bobkq cobnrbk`fbp0
Ik qefp obpb^o`e pqrav. qeb pb`lka qvmb lc riqo^plkf` pvpqbj e^p _bbk rpba0 Gbkbo^qlo. qo^kpar`bo. _llpqbo ^ka elok ^ob qeb j^glo `ljmlkbkqp lc qefp riqo^plrka bnrfmjbkq0
Teb b^pfbpq t^v ql fk`ob^pb qeb ^jlrkq lc riqo^plkf` mltbo ^s^fi^_ib clo ^ ob^`qflk fp ql mrq qeb c^`b lc ^k riqo^plkf` sf_o^qfkd qo^kpar`bo fk `lkq^`q tfqe qeb jbafrj0 Teb j^ufjrj qo^kpcbo lc mltbo dbkbo^qba _v ^ qo^kpar`bo fp ifjfqba _v qeb molmboqfbp lc qeb qo^kpar`bo j^qbof^i0 Teb ^jmifqrab molar`ba _v qeb qo^kpar`bo `^k _b ^jmif#ba _v ^qq^`efkd ^k riqo^plkf` elok0 Teb pbq lc qo^kpar`bo ^ka elok fp `^iiba mol_b pvpqbj0
Teb dbkbo^qlo
Teb dbkbo^qlo fp qeb plro`b lc ^iqbok^qfkd bib`qof`^i cobnrbk`v +qvmf`^iiv 42 hHw, lc qeb qo^kpar`bo0 Flo _bpq mbocloj^k`b. qeb mol_b pvpqbj jrpq _b qrkba _bclob _bfkd rpba0 Trkfkd fp qeb mol`bpp qeolrde tef`e qeb mol_b pvpqbj fp _olrdeq fkql qeb obplk^k`b `lkafqflk tfqe qeb qo^kpar`bo. ob^`efkd ^ jfkfjrj s^irb lc `fo`ri^qfkd `roobkq bsbk ^q cobnrbk`fbp af"bobkq colj 42 hHw0 Ic qeb pfwb lc qeb elok fp obar`ba _v bolpflk. qeb obplk^kq cobnrbk`v tfii s^ov0 Ik buqobjb `lkafqflkp. qeb qrkfkd tlk*q _b mlppf_ib ^ka pl qeb obmi^`bjbkq lc qeb elok pelria _b alkb0 Oofdfk^iiv qeb dbkbo^qlop tbob ^_ib ql `lsbo bib`qof`^iiv ^ dfsbk cobnrbk`v o^kdb tfqe pj^ii s^of^qflkp fk qrkfkd0 Iq fp ^ipl ob`ljjbkaba ql `^if_o^qb qeb mol_b pvpqbj fk ^fo lo fk kl / il^a `lkafqflkp0 Teb mobpbk`b lc il^a +ifnrfa fjjbopflk, obnrfobp ^aaba mltbo qe^q qeb dbkbo^qlo pelria molsfab ql qeb qo^kpar`bo0 Sljbqfjbp. ^ pvpqbj `^if_o^qba fk ^fo albp klq molsfab p^qfpc^`qlov mbocloj^k`b fkql ^ ob^`qflk jfuqrob0 Tefp l``rop bppbkqf^iiv ^q ilt fk sfp`lrp ifnrfap= fc. arofkd qeb riqo^plrka qob^qjbkq. qebob ^ob `e^kdbp fk mevpf`^i `e^o^`qbofpqf`p lc qeb jfuqrob. qeb mltbo clo j^fkq^fkfkd qeb lmqfjrj obplk^k`b `lkafqflkp jrpq _b `e^kdba ^ka ^ obqrkfkd lc qeb pvpqbj tfii _b obnrfoba0 Teb jlabok dbkbo^qlop `^k qlibo^qb ^ o^kdb lc cobnrbk`fbp jr`e i^odbo0 Sr`e pvpqbjp ^ob qrkba tebk qebv ^ob fjjbopba fk qeb jbafrj ^ka `^k _b ^agrpqba qeolrde ^ pbofbp lc bib`qof`^i absf`bp arofkd lmbo^qflk0 Teb `lkqoli lc qeb mltbo molar`ba _v ^ dbkbo^qlo ^iiltp s^ov qeb bkbodv prmmifba ql qeb qo^kpar`bo / qvmf`^iiv rpfkd ^ p`^ib colj 2 ql 322)0 Teb rmmbo ifjfq mobsbkqp qeb lsboil^afkd ^ka co^`qrobp lc mfbwl`bo^jf` bibjbkqp0
Teb mol_b pvpqbj `^k tloh fk `v`ibp pbqqfkd ^ plkf`^qflk mripb0 Teb mltbo `^k _b prmmifba ql qeb mol_b _v ^ qfjbo `lkkb`qba ql qeb ^jmif#bo0
Teb qo^kpar`bo
Teb qo^kpar`bo `lksboqp qeb bib`qof`^i lo jb`e^kf`^i bkbodv ql efde cobnrbk`v plrka t^sbp [44]0 Teobb j^fk qvmbp lc qo^kpar`bop `^k _b fabkqf#ba<
#!#! 0IC;8B<CH8AG D= IAHF8GDIC; HF<8HB<CH +
& \d^p / aofsbk(< qebv ^ob `e^o^`qbofwba _v efde cobnrbk`v lrqmrq ^ka mllo b%`fbk`v lc ^`lrpqf` bkbodv qo^kpcbo colj ^ d^p ql ^ ifnrfa0 Hltbsbo. qebv j^v _b rpba ql l_q^fk qeb ^qljfw^qflk lc qeb ifnrfa=
& \ifnrfa / aofsbk(< qebv dbkbo^qb `^sfq^qflk qeolrde qeb jlsbjbkq lc ^ ifnrfa fkpqb^a lc ^ d^p0 A mrjm clo`bp ^ jfuqrob ql m^pp qeolrde ^k lof#`b ^q efde pmbba0 Teb gbq `ljfkd lrq _rjmp fkql ^ pq^fkibpp pqbbi _i^ab0 Terp. `^sfq^qflk `^k _b molar`ba bfqebo _v Vbkqrof b"b`q +tebk qeb ifnrfa `ljfkd lrq lc qeb lof#`b bum^kap nrf`hiv fk ^ i^odbo slirjb, lo _v qeb sf_o^qflk lc qeb _i^ab lk tef`e qeb ifnrfa gbq fjm^`qp0 Sfk`b qeb ifnrfa. `ljb lrq lc ^k lof#`b. bum^kap nrf`hiv fk ^ i^odbo slirjb lo _v qeb sf_o^qflk lc qeb _i^ab lk tef`e qeb ifnrfa gbq fjm^`qp0 Teb `^sfq^qflk^i b"b`qp `^k _b `lkqoliiba _v ^agrpqfkd qeb lof#`b pfwb. qeb mobpprob lo qeb obi^qflkpefm _bqtbbk lof#`b ^ka _i^ab=
& \bib`qoljb`e^kf`^i(< qebpb qo^kpar`bop ^ob buqobjbiv sbop^qfib ^ka rpb qeb j^d/ kbqf` lo qeb mfbwlbib`qof` b"b`q [45]0 Ik j^dkbqlpqof`qfsb qb`ekfnrb. qeb bib`qof`^i bkbodv fp `lksboqba ql jb`e^kf`^i bkbodv lo sf_o^qflk tfqe ^ j^dkbqf` `lfi ^qq^`eba ql sf_o^qfkd mfb`b ifhb kf`hbi ^ka Tbocbkli/D0 M^dkbqf` qo^kpar`bop rpb qeb molm/ boqfbp lc `boq^fk j^qbof^ip +bd0 kf`hbi, ql obar`b qebfo pfwb tebk qebv ^ob fjjbopba fk ^ j^dkbqf` #bia ^ka ql obqrok ql lofdfk^i pfwb ^cqbo objlsfkd qeb #bia fqpbic0 Bv ^mmivfkd ^ j^dkbqf` #bia ^p ^ pr``bppflk lc peloq mripbp ql ^ j^dkbqlpqof`qfsb j^qbof^i. fq sf_o^qbp ^q qeb p^jb cobnrbk`v lc qeb ^mmifba #bia0 Tl ^slfa j^dkbqf` ilppbp. qtl plibklfap ^ob `lkkb`qba ql cloj ^ ofkd0 Sr`e pvpqbjp ^ob buqobjbiv ol/ _rpq ^ka aro^_ib0 Hltbsbo. qebob ^ob qtl afp^as^kq^dbp0 Ffopq. qeb rmmbo ifjfq lc cobnrbk`fbp fp 322 hHw. s^irb _bvlka tef`e qeb jbq^i albp klq obpmlka moljmqiv ql qeb j^dkbqlpqof`qflk0 Sb`lkaiv. qeb mltbo b%`fbk`v fp ibpp qe^k 82). tfqe pfdkf#/ `^kq eb^q ilppbp0 Flo qefp ob^plk. ^ii j^dkbqf` qo^kpar`bop obnrfob ^ $rfa `llifkd0 Ik qeb mfbwlbib`qof` qb`ekfnrb. qeb bib`qof`^i bkbodv fp `lksboqba ql efde cobnrbk`v bib`qof` bkbodv tfqe mfbwlbib`qof` `ovpq^ip ^qq^`eba ql ^ sf_o^qfkd mfb`b qe^q abifsbop qeb riqo^plrka t^sbp fkql qeb ifnrfa0 Pfbwlbib`qof` qo^kpar`bop ^ob jlpq `ljjlkiv rpba clo riqo^plrka dbkbo^qflk0 Mloblsbo. qebv ^ob jlob b%`fbkq +lsbo ;7), ^ka qebv lmbo^qb lsbo ^ i^odbo o^kdb lc cobnrbk`fbp +colj 42 hHw ql pbsbo^i MHw,0 Teb _llpqbo
Teb _llpqbo ^jmif#bp qeb sf_o^qflk +^jmifqrab, dbkbo^qba _v qo^kpar`bo fk loabo ql ob^`e qeb elok [44]0 Df"bobkq `lk#dro^qflkp lc elokp `^k _b #uba ql qeb _llpqbo0
Teb elok
Teb elok ^iiltp qeb qo^kpjfppflk lc sf_o^qflkp colj qeb ^jmif#bo qeolrde ^k ^aaf/ qflk^i mfb`b lc jbq^i qe^q ^jmifcv qeb mltbo afpqof_rqba ql qeb pvpqbj0 Teb jlabok mol_b pvpqbjp e^sb _bbk abpfdkba clo ^ pbofbp lc mol_bp. b^`e lc tef`e l"bop af"bobkq mltbo ^jmif#bop0 Se^mb ^ka pfwb ^ob qtl sbov fjmloq^kq `e^o^`qbofpqf`p lc ^ elok0 Teb plkf`^qflk fkqbkpfqv `^k _b `lkqoliiba _v ^iqbofkd qeb mltbo fkmrq ^ka fq fp _^pba lk qeb mol_b abpfdk0 Teb plkf`^qflk fkqbkpfqv tfii abqbojfkb qeb j^dkfqrab lc qeb d^fk lo jb`e^kf`^i ^jmif#`^qflk lc qeb sf_o^qflk0 Okb lc qeb j^glo abpfdk `ofqbof^ lc qeb elok fp
#" #! 6?<DFK
rkfclojfqv lc ^jmifqrab0 Ukfclojfqv fp af%`riq ql l_q^fk tfqe i^odb _il`h elokp0 M^ppbp ^ob lcqbk ^aaba ql qeb _^`h aofsb lc qebpb elokp lo rkabo`rqp ^ob j^ab kb^o qeb c^`b lc qeb elok tebob rkfclojfqv aolmp l"0 Ik ^aafqflk. tfqe i^odbo elokp. qeb pl/`^iiba \Plfpplk( b"b`q `^k molar`b rkabpfoba jlabp lc sf_o^qflk0 Sljb qvmf`^i elok abpfdkp ^ob peltk fk Ffdrob 3050
Ffdrob 305< Tvmbp lc elokp rpba fk riqo^plkf` qob^qjbkq
C^sfq^qflk `^rpbp qeb bolpflk lc qeb bka lc qeb mol_b pvpqbj0 Tebobclob. qeb jlpq mol_bp ^ob j^ab lc qfq^kfrj ^iilv0 Okb lc qeb j^glo b"b`qp lc qeb bolpflk fp obmobpbkqba _v qeb mevpf`^i peloqbkfkd lc qeb elok rkqfi fq ob^`ebp ^ ibkdqe ibpp qe^k R(* tef`e `^rpbp ilppbp fk b%`fbk`v0 Teb mol_b pvpqbjp ^ob qeb jlpq b%`fbkq jbqela ql qo^kpjfq riqo^plkf` bkbodv ql ^ ob^`qflk0 Aiqelrde qeb ^s^fi^_ib mltbo fp jr`e efdebo tfqe ^ mol_b pvpqbj. qeb `lpqp ^ob `lkpfabo^_ib0 Webk ^ mol_b pvpqbj fp rpba. pbsbo^i c^`qlop jrpq _b `lkpfaboba<
& qeb sli^qfib `ljmlkbkqp `^k _b b^pfiv ilpq fk ^k lmbk ob^`qlo _b`^rpb lc qeb ab/ d^ppfkd b"b`q lc riqo^plkf`^qflk=
& qeb i^odb ^jlrkq lc eb^q. dbkbo^qba _v mol_bp. `^k obnrfob ^ `llifkd=
& tebk efde/bkbodv riqo^plrkap ^ob ^mmifba ql ^ ifnrfa. qeb prmmifba mltbo `^k mol/ ar`b ^ `^sfq^qflk qe^q _il`hp qeb ^aafqflk^i mltbo bkqov0 Ik qefp `^pb. qeb pbqqfkd lc qeb `lkqoli absf`b lc mltbo ql qeb j^ufjrj s^irb albp klq kb`bpp^ofiv molar`b ^k efdebo plkl`ebjfpqov b"b`q=
#!#! 0IC;8B<CH8AG D= IAHF8GDIC; HF<8HB<CH ##
& ilt mltbo fkmrq `lria obnrfob jb`e^kf`^i jfufkd0 Aq efdebo mltbo fkmrqp. sf_o^qfkd/ bka qfm tfii molar`b bklrde jfufkd lc qeb ifnrfa _v fqpbic=
& `ebjf`^i ob^`qflkp j^v obnrfob pb^iba bnrfmjbkq. pilt ^aafqflk lc ob^dbkqp lo fk/ boq ^qjlpmebobp0 Tebpb plkl`ebjfpqov ob^`qflkp pelria _b `lkar`qba fk pmb`f#` sbppbip0
-CT@LR@FDQ @LC CHQ@CT@LR@FDQ ME SJRP@QMLHB NPMAD QVQRDKQ
Cljjbo`f^i riqo^plkf` mol_bp ^ob dbkbo^iiv rpba ql ^mmiv m^oqf`ri^oiv efde mltbo riqo^/ plrkap fk ^ `ebjf`^i ob^`qflk0
Bbkb#qp
Teb riqo^plkf` mltbo. molsfaba _v qeb mol_b. fp afob`qiv obi^qba ql qeb sf_o^qflk^i tfaqe lc efp bka0 Tefp `^k _b b^pfiv bs^ir^qba `lkqoliifkd qeb fkmrq mltbo ql qeb qo^kp/ ar`bo0 Teb riqo^plrka `roobkq. dbkbo^qba ^q qeb bka lc qeb elok. fp lcqbk bklrde ql molsfab b"b`qfsb jfufkd lc qeb ifnrfa j^pp. ^iob^av lmbo^qfkd ^q jlabo^qb mltbo0 Mla/ bok absf`bp ^iilt qeb ob^ifw^qflk lc plkf`^qflk `v`ibp qe^q ^ob obmb^qba clo co^`qflkp lc ^ pb`lka0 Iq molsfabp ^k ^abnr^qb qfjb clo `llifkd _bqtbbk qtl pr_pbnrbkq plrka mripbp0 Teb pvpqbj `^k _b ^abnr^qbiv qrkba fk loabo ql molsfab qeb _bpq mbocloj^k`b0 Tefp fp m^oqf`ri^oiv fjmloq^kq clo obmolar`f_fifqv lc obpriqp0 Teb jlabok riqo^plrka pvpqbjp rpr^iiv e^sb ^ absf`b clo ^rqlj^qf` cobnrbk`v `lkqoli0
Dfp^as^kq^dbp
Ap ^ii absf`bp qe^q rpb mfbwlbib`qof` qo^kpar`bop. qeb _bpq mbocloj^k`bp ^ob ^`efbsba ^q ^ #uba cobnrbk`v0 Smb`f^i mob`^rqflkp pelria _b q^hbk ql bkprob ^abnr^qb qbjmbo^qrob `lkqoli fk p^jmibp0 Flo qefp mromlpb. fq fp m^oqf`ri^oiv `lksbkfbkq qeb ^almqflk lc pmb`f#` ob^`qlo pe^mb +bd0 Rlpbqq `bii,0 Ik qeb ob^`qlo qeb qbjmbo^qrob pelria _b jlkfqloba `lkqfkrlrpiv0 Drb ql qeb o^af^qflk fkqbkpfqv kb^o qeb bka lc qeb elok. o^af`^ip j^v _b molar`ba0 Teb `^sfq^qflk `^k molar`b qeb `loolpflk lc qeb elok buqobjfqv. ^iqelrde fq fp j^ab lc qfq^kfrj0 Ttl mol_ibjp. obi^qba ql mol_b `loolpflk. `^k _b fabkqf#ba<
& qeb jbq^i m^oqf`ibp. objlsba colj qeb mol_b. `^k `lkq^jfk^qb qeb ob^`qflk jfuqrob= & qeb peloqbkfkd lc qeb elok `^k `^rpb ^ ilpp fk mol_b b%`fbk`v0 Teb mol_ibj `^k eltbsbo _b plisba b`lkljf`^iiv rpfkd obmi^`b^_ib bkap qe^q ^slfa qeb obmi^`bjbkq lc bkqfob elok0
,),)/
CW_NZ JVM NVNZPa Y]JV\R"LJ\RWV
Teb b`lkljf` `lksbkfbk`b lc ^k riqo^plrka pvpqbj fp dlsbokba _v qeb mltbo lo bkbodv rpba ql ^`efbsb piradb afpfkqbdo^qflk0 Terp. qeb nr^kqf#`^qflk lc bkbodv1mltbo fkmrq fp `ofqf`^i ql bs^ir^qb qeb riqo^plrka qob^qjbkq b%`fbk`v0
Teb mltbo lo bkbodv prmmifba clo piradb afpfkqbdo^qflk `^k _b bumobppba fk ^ krj_bo lc t^vp ^p dfsbk fk T^_ib 3040 Teb prmmifba mltbo lo pmb`f#` bkbodv abmbkap lk _lqe piradb `e^o^`qbofpqf`p ^ka riqo^plrka pvpqbj abpfdk0
#$ #! 6?<DFK
T^_ib 304< Eumobppflkp ql nr^kqfcv piradb afpfkqbdo^qflk
9@P@KDRDP 1UNPDQQHML =LHR :DEDPDLBD
Smb`f#` prmmifba bkbodv )/>, "* )' "; hJ1hdTS Fbkd bq ^i0 +422;, [46]
Uiqo^plrka alpb 5 ($>' ";, J1L Tfbej bq ^i0 +4223, [8]
Uiqo^plrka abkpfqv 5 (> '
, W1L Tfbej bq ^i0 +4223, [8]
Uiqo^plrka fkqbkpfqv 5 ,> '
! W1`j
& Nbfp bq ^i0 +4222, [47]
P > mltbo fkmrq +hW,= q > plkf`^qflk qfjb +p,= V > piradb slirjb +L,= A > mol_b proc^`b ^ob^ +`j&,= TS > qlq^i plifa `lk`bkqo^qflk +hd1L,
,),)0
:^JT]J\RWV WO ]T\ZJ[W]VM MR[RV\NPZJ\RWV N$LRNVLa
Teb jf`ol_r__ib fjmilpflkp molar`b mevpf`^i ^ka `ebjf`^i ob^`qflkp qe^q `^k jlafcv qeb `e^o^`qbofpqf`p lc afpplisba ^ka m^oqf`ri^qb j^qqbo mobpbkq fk qeb jbafrj0 Terp. piradb afpfkqbdo^qflk `^k _b bs^ir^qba _v `e^kdbp fk mevpf`^i ^ka `ebjf`^i molmboqfbp0
Pevpf`^i `e^o^`qbofpqf`p pr`e ^p m^oqf`ib pfwb. pbqqib^_fifqv. qro_fafqv ^ka abt^qbo^_fifqv ^ob rpba ^p nr^ifq^qfsb jb^probjbkq lc piradb afpfkqbdo^qflk0 Uiqo^plrkap afpfkqbdo^qb piradb m^oqf`ibp ql ^ sbov pj^iibo pfwb ^ka i^pbo af"o^`qflk fp rpr^iiv rpba clo m^oqf`ib pfwb ^k^ivpfp0 Teb qro_fafqv lc piradb `e^kdbp tfqe fk`ob^pb fk plkf`^qflk m^o^jbqbop +riqo^plrka abkpfqv. riqo^plrka fkqbkpfqv ^ka plkf`^qflk qfjb, ^ka fq fp jb^proba _v rpfkd ^ qro_fafjbqbo0 Teb piradb abt^qbo^_fifqv fp jb^proba _^pba lk qeb `^mfii^ov pr`qflk qfjb +CST, ^ka pmb`f#` obpfpq^k`b lc #iqo^qflk +SRF,0
Cebjf`^i bs^ir^qflk fp ;2) jlob nr^kqfq^qfsb ^ka j^fkiv _^pba lk abdobb lc afp/ fkqbdo^qflk +DD, m^o^jbqbo abqbojfk^qflk0 Teb _ob^haltk lc _^`qbof^i `bii t^iip _v afpormqflk `^k _b ^ppbppba _v rpfkd _flildf`^i rqfifw^qflk qbpqp0
9GVQHB@J DT@JS@RHML
Pevpf`^i bs^ir^qflk. pr`e ^p m^oqf`ib pfwb ^k^ivpfp. jf`olp`lmf` l_pbos^qflkp. qro_fafqv ^ka piradb abt^qbo^_fifqv e^p _bbk tfabiv rpba ql bs^ir^qb piradb afpfkqbdo^qflk0
Tfbej bq ^i0 [48] clrka qe^q. tfqe fk`ob^pb fk plkf`^qflk qfjb. qeb m^oqf`ib pfwb obar`ba do^ar^iiv colj 387 "j ql 357 "j ^ka :7 "j tfqe ^ 206; jfkrqbp ^ka 308 jfkrqbp plkf`^qflk qfjb. obpmb`qfsbiv0
#!#! 0IC;8B<CH8AG D= IAHF8GDIC; HF<8HB<CH #%
_bvlka tef`e qeb m^oqf`ib pfwb fk`ob^pba do^ar^iiv tfqe fk`ob^pb fk plkf`^qflk qfjb0 Teb fk`ob^pb fk jbaf^k af^jbqbo. l_pbosba fk ilkd/aro^qflk qob^qjbkqp. `^k _b molar`ba _v qeb obib^pb lc fkqo^`biiri^o mlivjbop arb ql `bii ivpfp qe^q ^ob c^slro^_ib clo ob/$l``ri^qflk0 Cer bq ^i0 [4:] bu^jfkba qeb b"b`q lc af"bobkq plkf`^qflk abkpfqfbp ^ka qfjbp lk $l` pfwb afpqof_rqflk ^q 42 KHw cobnrbk`v ^ka 332 W j^ufjrj mltbo fkmrq0 Teb fk`ob^pb fk plkf`^qflk abkpfqv fk`ob^pba qeb afpfkqbdo^qflk b%`fbk`v0 Teb $l` pfwb obar`ba colj ;:0; "j ql 44 "j ^ka ibpp qe^k 5 "j tfqe ^ 2055 W1jL ^ka 2066 W1jL clo ^ 42 jfkrqbp plkf`^qflk qfjb0 Bv fk`ob^pfkd plkf`^qflk qfjb rm ql 342 jfkrqbp. kl $l` pfwb ab`ob^pb _bvlka 5 "j e^p _bbk l_pbosba0
Blrdofbo bq ^i0 [9] bs^ir^qba qeb m^oqf`ib pfwb afpqof_rqflk ^q af"bobkq pmb`f#` bkbodv fkmrqp rpfkd 42 hHw cobnrbk`v ^ka 447 W prmmifba mltbo fkmrq0 P^oqf`ib pfwb o^kdba colj 206 ql 3222 "j0 Teb slirjb l``rmfba _v pj^ii m^oqf`ibp fk`ob^pba tfqe qeb pmb`f#` prmmifba bkbodv0 Flo Ep>36772 hJ1hdTS m^oqf`ibp lc 3 jj l``rmfba 307 ) lc qeb telib slirjb. tebob^p qebv l``rmfba 203 ) fk qeb rkqob^qba p^jmib0 Ok qeb lqebo e^ka. qeb slirjb l``rmfba _v m^oqf`ibp _fddbo qe^k 322 "j fk`ob^pba i^odbiv tfqe pmb`f#` prmmifba bkbodv0 Tefp `lria _b bumi^fkba _v ^ ob/$l``ri^qflk mebkljbklk. ^iob^av l_pbosba _v Glkwb bq ^i0 [49]0
Gbkbo^iiv. ^p clrka _v Selt bq ^i0 [4;]. m^oqf`ibp i^odbo qe^k 606 "j buef_fqba qeb jlpq fkqbkpb afpormqflk fk qeb fkfqf^i 3 jfkrqb ^ka qeb afpormqflk _b`^jb j^odfk^i lk croqebo plkf`^qflk qfjbp0 Iq ^mmb^oba qe^q jf`ol/$l`p +$606 "j, tbob ibpp prp`bmqf_ib ql riqo^plkf` afpormqflk qe^k j^`ol/$l`p +%606 "j,0 Teb _fkafkd clo`bp fk jf`ol/$l`p. pr`e ^p `biip. ^ob jr`e pqolkdbo qe^k qelpb fk j^`ol/$l`p qe^q ^ob j^ab rm lc ^ jlob illpbiv _lrka ^ddobd^qflk0 Iq fp ^ipl ifhbiv qe^q j^`ol/$l`p e^sb i^odbo proc^`b ^ob^p bumlpba ql qeb plkf`^qflk qe^q `^k molar`b ^ dob^qbo buqbkq lc afpormqflk0 Teb `e^kdb fk $l` pqor`qro^i fkqbdofqv ^q af"bobkq plkf`^qflk qfjbp `^k _b l_pbosba rpfkd jf`olp`lmf` bu^jfk^qflk0 Hltbsbo. ^ ifdeq_^pba jf`oldo^me albp klq molsfab fkcloj^qflk ^q `biiri^o ibsbi0 Ke^k^i bq ^i0 [52] plkf`^qba ^ t^pqb ^`qfs^qba piradb. `e^o^`qbofwba _v ^ i^odb krj_bo lc #i^jbkqp. clo 4 jfkrqbp ^ka clrka qe^q qeb #i^jbkqp ^ka qeb $l`p tbob ^ijlpq `ljmibqbiv afpfkqbdo^qb0
Ok qeb lqebo e^ka. Fbkd bq ^i0 [46] l_pbosba qe^q $l` pqor`qrob t^p do^ar^iiv afp/ ormqba _rq klq qlq^iiv afpfkqbdo^qba. bsbk ^q bkbodv alp^dbp efdebo qe^k 48222 hJ1hdST0 Tl molsfab fkcloj^qflk ^q `biiri^o ibsbi p`^kkfkd bib`qolk jf`oldo^mep jrpq _b rpba0 Gbkbo^iiv. qeb piradb qro_fafqv fk`ob^pbp tfqe fk`ob^pb fk pmb`f#` prmmifba bkbodv ^ka fq fp afob`qiv `loobi^qba ql m^oqf`ib pfwb obar`qflk [8]0
Fbkd bq ^i0 [46] bs^ir^qba qeb fk$rbk`b lc pmb`f#` bkbodv lk piradb qro_fafqv0 Teb prmbok^q^kq qro_fafqv lc qob^qba piradb ab`ob^pba clo prmmifba pmb`f#` bkbodv iltbo qe^k 7222 hJ1hdTS `ljm^oba ql qeb rkqob^qba lkb0 Hltbsbo. ^q prmmifba pmb`f#` bkbodv efdebo qe^k 7222 hJ1hdTS. qro_fafqv t^p ao^pqf`^iiv fk`ob^pba0 Tefp t^p jlpq ifhbiv ^qqof_rq^_ib ql fk`ob^pbp fk qeb ^jlrkq lc jf`ol/m^oqf`ibp obib^pba colj piradb $l`p fkql qeb prmbok^q^kq ^q efde/bkbodv alpbp0 Cer bq ^i0 [4:] `lk`iraba qe^q riqo^plkf` qob^qjbkq e^p kl fk$rbk`b lk piradb pbqqib^_fifqv. tef`e `lkqo^af`qp qeb `e^kdbp fk m^oqf`ib pfwb ^ka $l` pqor`qrob ^cqbo plkf`^qflk0
Fbkd bq ^i0 [46] bs^ir^qba pbqqifkd sbil`fqv ^q af"bobkq bkbodfbp0 Teb pbqqifkd sbil`fqv s^irbp lc 722 ^ka 3222 hJ1hdTS qob^qba piradbp tbob dob^qbo qe^k qe^q lc rkqob^qba piradb0 Ok qeb lqebo e^ka. _v fk`ob^pfkd qeb pmb`f#` bkbodv lsbo 3222 hJ1hdTS. qeb pbq/
#& #! 6?<DFK
qifkd sbil`fqv t^p iltbo fk qob^qba piradbp `ljm^oba ql rkqob^qba lkb0 Froqebo fk`ob^pbp fk pmb`f#` bkbodv iba ql ab`ob^pb fk pbqqifkd sbil`fqv0 Tefp obar`qflk t^p mol_^_iv ifkhba ql $l` pfwb obar`qflk ^ka lod^kf` pr_pq^k`bp obib^pba fkql ifnrfa me^pb ^q efde pmb`f#` bkbodfbp0 Tebobclob. qeb ^rqelop prddbpqba ^ pmb`f#` bkbodv lc 3222 hJ1hdTS ^p lmqfjrj clo pbqqifkd sbil`fqv fjmolsfkd0 Lltbo mltbo ibsbi tfqe peloq plkf`^qflk qfjb fk`ob^pbp abt^qbo^_fifqv. _rq fq ab`ob^pbp qeb abdobb lc afpfkqbdo^qflk0
Cer bq ^i0 [4:] l_pbosba qe^q abt^qbo^_fifqv ab`ob^pba tfqe fk`ob^pb fk plkf`^qflk qfjb _b`^rpb ^ dob^q ^jlrkq lc t^qbo `lria _b ^qq^`eba lkql qeb i^odb proc^`bp molsfaba _v qeb pj^ii m^oqf`ibp ^cqbo riqo^plkf`^qflk0
Glkwb bq ^i0 [49] clrka qe^q piradb abt^qbo^_fifqv fk`ob^pba tfqe iltbo plkf`^qflk mltbo ibsbi ^ka ibpp plkf`^qflk qfjb. _rq tfqe ^k fk`ob^pb fk plkf`^qflk qfjb ^q p^jb mltbo ibsbi. abt^qbo^_fifqv ab`ob^pba0 Tefp fp arb ql qeb c^`q qe^q qeb $l`p afa klq obar`b ql pj^iibo m^oqf`ibp ^q iltbo mltbo ibsbip ^ka tfqe ibpp plkf`^qflk qfjb0
/GDKHB@J DT@JS@RHML
Cebjf`^i bs^ir^qflk fp c^o jlob nr^kqfq^qfsb clo jb^profkd piradb afpfkqbdo^qflk qe^k mevpf`^i lkb0 Iq jb^probp qeb plir_fifw^qflk lc t^pqb ^`qfsbqba piradb fk qeb ^nrblrp me^pb0 Ik bksfolkjbkq^i bkdfkbbofkd. ^ii obib^pba lod^kf` j^qqbo fp jb^proba ^p ^k fk`ob^pb fk plir_ib `ebjf`^i luvdbk abj^ka +pCOD,0 Uiqo^plkf` mobqob^qjbkq ^ipl afp/ fkqbdo^qbp buqo^`biiri^o j^qqbo fk`irafkd lod^kf` ab_ofp ^ka buqo^`biiri^o mlivjbof` pr_/ pq^k`bp +ESP,. tef`e ^ipl _b`ljb m^oq lc pCOD0 Terp. pCOD fp ^ dolpp m^o^jbqbo ql nr^kqfcv qeb piradb afpfkqbdo^qflk [53]0 M^kv ^rqelop e^sb `elpbk pCOD ^p ^ m^o^jbqbo ql bs^ir^qb qeb piradb afpfkqbdo^qflk0 Hltbsbo. fq fp e^oa ql `ljm^ob lkb pqrav ql qeb lqebo _b`^rpb riqo^plkf` afpfkqbdo^qflk abmbkap lk pbsbo^i c^`qlop pr`e ^p TS `lkqbkq. cobnrbk`v. piradb qvmb. riqo^plkf` abkpfqv. qbjmbo^qrob ^ka plkf`^qflk qfjb0 Flo _bqqbo `ljm^ofplk. qeb pCOD obib^pb kbbap ql _b `loobi^qba tfqe qeb pmb`f#` bkbodv fkmrq0 Ui/ qo^plrka qob^qjbkq e^p kl b"b`q lk qeb qlq^i COD +qCOD,0 Tebobclob. qeb pCOD1qCOD o^qfl obmobpbkqp qeb obib^pb lc qeb lod^kf` j^qqbo colj plifa pq^qb ql ifnrfa pq^qb ^cqbo riqo^plrka qob^qjbkq0 Am^oq colj pCOD. ^jjlkf^ kfqoldbk. lod^kf` kfqoldbk ^ka EPS `lk`bkqo^qflkp +mlivp^``e^ofabp. molqbfkp. kr`ibf` ^`fap. ifmfap ^ka lqebo mlivjbof` `lj/ mlrkap, ^ob ^ipl fjmloq^kq m^o^jbqbop clo `ebjf`^i bs^ir^qflk lc riqo^plrka qob^qjbkq0 COD abqbojfk^qflk fp rpbcri ql l_q^fk qeb abdobb lc afpfkqbdo^qflk +DD, m^o^jbqbo. tef`e #opq t^p molmlpba ql nr^kqfcv qeb piradb afpfkqbdo^qflk ^p dfsbk _v qeb cliiltfkd bnr^qflk 303030 ((>! '0(<5;9-:8<70! '0(894247-5 '0(% -&$""!"! '0(% -&$! " ! '0(% -&$! '0(38682174?-;487 " # 322+), +30303, Webob<
& COD<5;9-:8<70 fp qeb COD lc prmbok^q^kq lc riqo^plrka qob^qba p^jmib +jd1L,=
& COD894247-5 fp qeb COD lc prmbok^q^kq lc lofdfk^i +rkqob^qba, p^jmib +jd1L,=
& COD% -&$""!" fp qeb COD lc prmbok^q^kq ^q 44 e ^cqbo ^aafqflk lc 3 M N^OH
#!#! 0IC;8B<CH8AG D= IAHF8GDIC; HF<8HB<CH #'
& COD% -&$! qeb COD lc prmbok^q^kq ^q qfjb wbol ^cqbo ^aafqflk lc 3 M N^OH
+jd1L,=
& COD% -&$! qeb COD lc p^jmib ^cqbo ^aafqflk lc 3M N^OH +jd1L,=
& COD38682174?-;487 qeb COD lc lofdfk^i p^jmib ^cqbo eljldbkfw^qflk +jd1L,0
Teb qboj +COD<5;9-:8<70 / COD894247-5, obmobpbkqp qeb plir_ib COD obib^pba _v ri/
qo^plkf` afpfkqbdo^qflk ^ka qeb qboj +COD% -&$""!" / COD% -&$!, obmobpbkqp plir_ib
COD obib^pba _v `ebjf`^i afpfkqbdo^qflk0 Teb COD obib^pba _v N^OH ^aafqflk +`ebj/ f`^i afpfkqbdo^qflk, fp ^pprjba ql obpriq fk `ljmibqb afpfkqbdo^qflk lc piradb ^ka fq fp rpba ^p ^ obcbobk`b COD0 Teb o^qfl lc COD% -&$! ^ka COD38682174?-;487 obmobpbkqp
qeb COD lc qeb p^jmib _bclob ^ka ^cqbo ^aafqflk lc 3M N^OH fk qeb o^qfl lc 3<507 ^q 42$C0 Mriibo molmlpba ^ jlaf#ba sbopflk lc mob`bafkd bnr^qflk ql `^i`ri^qb DD [54] ^p
cliilt 30304< ((>! '0(<5;9-:8<70! '0(894247-5 '0(% -&$! '0(894247-5 " # 322+), +30304, tebob<
& COD<5;9-:8<70 fp qeb COD fk qeb prmbok^q^kq lc qeb plkf`^qba p^jmib +jd1L,=
& COD894247-5 fp qeb COD lc prmbok^q^kq lofdfk^i +rkqob^qba p^jmib, +jd1L,=
& COD% -&$ fp qeb j^ufjrj COD obib^pb fk qeb prmbok^q^kq ^cqbo N^OH afdbpqflk
+jd1L,0
Teb N^OH afdbpqflk fp `^oofba lrq _v qob^qfkd qeb piradb p^jmibp tfqe 3M N^OH fk qeb o^qfl lc 3<4 clo 32 jfk ^q ;2$C0 Teb prmbok^q^kq fp l_q^fkba _v `bkqofcrd^qflk clo
32 jfk ^q 52222 d ^ka ^ qbjmbo^qrob lc 6$C0 Tfbej bq ^i0 [8] ^ka R^f bq ^i0 [55] rpba
qeb abdobb lc afpfkqbdo^qflk +DD, jlaf#ba _v Mriibo clo bs^ir^qfkd qeb afpfkqbdo^qflk b%`fbk`v0 A DD lc 62) t^p l_q^fkba _v Tfbej bq ^i0 [8] ^q ^ 82222 hJ1hdTS pmb`f#` prmmifba bkbodv= tebob^p R^f bq ^i0 [55] obmloqba ^ DD lc 47) ^q 86222 hJ1hdTS bkbodv fkmrq0 Sr`e s^of^qflkp ^ob jlpq ifhbiv ^qqof_rqba ql bkbodv qo^kpcbo b%`fbk`v lc riqo^plkf` rkfqp0
A ifkb^o `loobi^qflk _bqtbbk abdobb lc afpfkqbdo^qflk ^ka ^mmifba riqo^plkf` fkqbkpfqv t^p l_pbosba _v Nbfp bq ^i0 [47]0 Teb abdobb lc afpfkqbdo^qflk t^p jlob qe^k alr_iba _v fk`ob^pfkd qeb fkqbkpfqv colj 8W1`j&ql 3:W1`j&0 Teb efdebo jb`e^kf`^i peb^o clo`bp
molar`ba ^q efdebo fkqbkpfqfbp ormqrobp qeb jf`ollod^kfpjp `bii t^iip fk`ob^pfkd pCOD `lk`bkqo^qflk0
Nbfp bq ^i0 [47] ^ipl bs^ir^qba qeb b"b`q lc TS `lkqbkq `lk`bkqo^qflk lk pCOD obib^pb0 Teb pCOD obib^pb fk`ob^pbp tfqe TS `lkqbkq fk`ob^pfkd rkqfi ^k lmqfjrj. _bvlka tef`e pCOD ao^j^qf`^iiv ab`ob^pbp arb ql ^qqbkr^qflk b"b`qp0 Mloblsbo. W^kd bq ^i0 [37] obmloqba ^ pfdkf#`^kq pCOD obib^pb colj 6222 ql ;222 jd1L tebk qeb TS `lkqbkq fp fk`ob^pba colj 207 ql 3) arofkd 52 jfk lc plkf`^qflk ^q ^k riqo^plkf` abkpfqv lc 3066 W1jL0
#( #! 6?<DFK
Ke^k^i bq ^i0 [53] bs^ir^qba qeb b"b`q lc TS `lkqbkqp lk pCOD obib^pb ^q af"bobkq pmb`f#` bkbodv fkmrqp0 Teb pCOD obib^pb fk`ob^pbp tfqe fk`ob^pfkd fk _lqe TS `lkqbkq ^ka bkbodv fkmrq0 Hltbsbo. qeb pCOD obib^pb piltp altk ^q efdebo 57 hJ1dTS bkbodv fkmrq clo ^ii TS `lkqbkqp0
Ahfk bq ^i0 [56] l_pbosba ^ pCOD obib^pb lc 552 jd1dTS ^q 4) TS ^ka 7 hWp1dTS pmb`f#` bkbodv fkmrq0 Hfdebo TS `lkqbkq albp klq fjmolsb qeb piradb afpfkqbdo^qflk0 Aq 6) ^ka 8) TS `lkqbkq. qeb pCOD obib^pb piltp altk pfdkf#`^kqiv0 Aq efdebo plifa `lk`bkqo^qflk jlob `^sfq^qflk pfqbp ^ob dbkbo^qba ^ka jlob m^oqf`ibp ^ob bumlpba ql qeb obpriqfkd peb^o clo`bp ^ka ql m^oqf`ib/ql/m^oqf`ib `liifpflk0 Ok qeb lqebo e^ka. qeb TS `lk`bkqo^qflk fk`ob^pb molar`bp ^k fk`ob^pb fk sfp`lpfqv0 A qll efde sfp`lpfqv efkabop `^sfq^qflk _r__ib cloj^qflk0
A``loafkd ql Selt bq ^i0 [4;]. ^q `lkpq^kq bkbodv fkmrq. qeb TS lmqfj^i `lkqbkq o^kdbp _bqtbbk 405) ^ka 504) TS0 Blrdofbo bq ^i0 [9] bs^ir^qba qeb b"b`q lc pmb`f#` bkbodv lk COD plir_fifw^qflk0 Teb pCOD1qCOD o^qb fk`ob^pba colj 6) ql 54) tfqe fk`ob^pb fk pmb`f#` bkbodv colj 2 hJ1hdTS ql 32222 hJ1hdTS tfqe ^k lmqfjrj ^q ^ pmb`f#` bkbodv lc 32222 hJ1hdTS0
Ok qeb lqebo e^ka. Ke^k^i bq ^i0 [52] l_q^fkba ^k pCOD1qCOD lc 3804) ^q ^ 88:22 hJ1hdTS bkbodv fkmrq0 Aiqelrde qeb abdobb lc plir_fifp^qflk fjmolsbp tfqe fk`ob^pb fk pmb`f#` prmmifba bkbodv. qeb fjmolsbjbkq fp klq fk afob`q molmloqflk ql qeb bkbodv fkmrq0 M^kv pqrafbp mobpbkqba qeb pCOD fk`ob^pb tfqe obpmb`q ql plkf`^qflk qfjb0 W^kd bq ^i0 [57] l_pbosba ^k fk`ob^pb fk pCOD obib^pb colj 47:3 ql 972; jd1L tebk qeb plkf`^qflk qfjb t^p fk`ob^pba colj 7 ql 37 jfk0 Hltbsbo. clo 42 jfk qob^qjbkq. qeb pCOD obib^pb piltba altk pfdkf#`^kqiv0
Sfjfi^o obpriqp tbob clrka _v Amri bq ^i0 [58]0 A 37 jfkrqbp riqo^plkf` qob^qjbkq bke^k`ba 72 jd1L pCOD rm ql ^ s^irb lc 4722 jd1L pCOD +6;22) pCOD fk`ob^pb,0 Llkdbo plkf`^qflk qfjb obpriqba fk pCOD $r`qr^qflkp0 Drofkd riqo^plrka ^mmif`^qflk. qeb qbjmbo^qrob do^ar^iiv olpb colj 42$C lc rkqob^qba p^jmib ql 92$C ^cqbo 37 jfkrqbp
riqo^plkf` qob^qjbkq0 Teb ab`ob^pb fk pCOD obib^pb t^p mol_^_iv arb ql qeb qeboj^i b"b`qp0
Teb ofpb fk qbjmbo^qrob iba ql efdebo p^qro^qba s^mlro mobpprob. tef`e j^ab fq e^oabo clo qeb s^mlro _r__ib ql `lii^mpb ^ka qerp ab`ob^pba qeb `^sfq^qflk fkqbkpfqv0 Teb b"b`q lc qbjmbo^qrob t^p ^ipl bs^ir^qba _v Cer bq ^i0 [4:]0 Teb qbjmbo^qrob lc qeb _rih plirqflk fk`ob^pba do^ar^iiv tfqe fk`ob^pb fk mltbo ibsbi ^ka plkf`^qflk qfjb. tef`e obpriqba fk ^k fk`ob^pb fk qeb pCOD1COD o^qfl0
Teb b^pb lc riqo^plkf` afpfkqbdo^qflk fp ^ipl dlsbokba _v qeb `ljmlpfqflk lc qeb piradb j^qofu0 Iq fp _bifbsba qe^q klk/_flildf`^i plifap. b0d0. mofj^ov piradb ^ka ^kfj^i j^krob. ^ob obi^qfsbiv b^pv ql afpfkqbdo^qb `ljm^oba ql _flildf`^i piradb pr`e ^p t^pqb ^`qfs^qba piradbp0
Rb`bkq pqrafbp e^sb cl`rpba lk qeb mlppf_fifqv lc rpfkd molqbfk ^k^ivpfp clo jb^profkd qeb piradb afpfkqbdo^qflk b%`fbk`v. pfk`b molqbfkp ^ob ^k fjmloq^kq _rfiafkd _il`h lc ^ii jf`ol_f^i `biip0 Teb jf`ol_f^i buqo^`biiri^o mlivjbof` pr_pq^k`bp +EPS,. tef`e molsfab qeb pqor`qro^i j^qofu clo ^ii jf`ol_f^i ^ddobd^qbp pr`e ^p $l`p fk ^`qfs^qba piradb. ^ipl `lkq^fk molqbfk [53]0
W^kd bq ^i0 [57] nr^kqf#ba qeb piradb afpfkqbdo^qflk _v molqbfk jb^probjbkq ^q af"bobkq plkf`^qflk qfjbp ^ka obmloqba ^ molqbfk `lkqbkqp lc 8;: ^ka 3355: jd1L fk EPS
#!$! 0IC;8B<CH8AG D= 8C8<FD9@: ;@><GH@DC #)
^ka fkpfab qeb jf`ol_f^i `biip. obpmb`qfsbiv0
Teb obib^pb lc ^jjlkf^ ^ka plir_ib lod^kf` kfqoldbk fk qeb ^nrblrp me^pb `lria _b ^klqebo rpbcri qlli ql ^ppbpp qeb riqo^plrka qob^qjbkq afpfkqbdo^qflk b%`fbk`v0
Ke^k^i bq ^i0 [59] pqrafba qeb ^jjlkf^/kfqoldbk obib^pb ^q af"bobkq TS `lkqbkqp ^ka pmb`f#` bkbodv fkmrqp0 Teb ^jjlkf^/kfqoldbk obib^pb fk`ob^pba tfqe fk`ob^pb fk pmb`f#` bkbodv fkmrqp ^ka TS `lkqbkqp0 Teb ^jjlkf^/kfqoldbk `lk`bkqo^qflk ob^`eba ^ c^foiv `lkpq^kq ibsbi ^q pmb`f#` bkbodv fkmrqp lc 42 hJ1dTS clo 402. 407 ^ka 5) TS `lkqbkqp ^ka 32 hJ1dTS clo 307) TS `lkqbkq0 Drofkd plkf`^qflk. _^`qbof^i `biip ^ob afpfkqbdo^qba ^ka fkqo^`biiri^o lod^kf` kfqoldbk t^p obib^pba fkql qeb ^nrblrp me^pb0 Teb lod^kf` kfqoldbk t^p pr_pbnrbkqiv evaolivwba ql ^jjlkf^0 Mloblsbo. qeb afpfkqbdo^qflk lc lod^kf` kfqoldbk colj klk/_flildf`^i ab_ofp `lria ^ipl `lkqof_rqb ql qeb ^jjlkf^ kfqoldbk obib^pb0
Blrdofbo bq ^i0 [9] jlkfqloba plir_ib lod^kf` ^ka ^jjlkf^ kfqoldbk obib^pb colj ^ qef`hbkba WAS. plkf`^qba ^q af"bobkq pmb`f#` bkbodv fkmrqp0 Teb qlq^i Kgbia^ei kfqol/ dbk +TKN, fk qeb telib piradb afa klq `e^kdb qeb pmb`f#` bkbodv fkmrqp ^q ^ii0 Tefp ^mm^obkqiv prddbpqp qe^q riqo^plrka albp klq `lkqof_rqb ql kfqoldbk jfkbo^ifw^qflk lo sli^qfifw^qflk0 Hltbsbo. lod^kf` kfqoldbk ^ka ^jjlkf^ kfqoldbk fk`ob^pba fk qeb ^nrb/ lrp me^pb tfqe fk`ob^pb fk qeb pmb`f#` bkbodv fkmrq arofkd plkf`^qflk tfqe `lk`ljfq^kq ab`ob^pb lc lod^kf` kfqoldbk fk qeb plifa me^pb0 Teb j^ufjrj plir_fifw^qflk lc lod^kf` kfqoldbk t^p ^`efbsba ^q ^ pmb`f#` bkbodv fkmrq lc 32 hJ1dTS0
Fbkd bq ^i0 [46] ^ipl l_pbosba qeb `e^kdbp fk ^jjlkfrj kfqoldbk ^ka kfqo^qb kfqoldbk `lk`bkqo^qflk ^q af"bobkq pmb`f#` bkbodv fkmrq0 Teb ^jjlkfrj kfqoldbk `lk`bkqo^qflk lc qeb prmbok^q^kq o^mfaiv fk`ob^pba tfqe fk`ob^pfkd bkbodv fkmrq0 Webk bkbodv fkmrq bu`bbaba 33 222 hJ1hdTS. qeb `lk`bkqo^qflk lc ^jjlkfrj kfqoldbk fk qeb prmbok^q^kq fk`ob^pba jlob qe^k 332). _rq ^mmif`^qflk lc 722 ^ka 3222 hJ1hdTS pqfii `^rpba fk`ob^pbp lc 53093) ^ka 49089). obpmb`qfsbiv0 Teb kfqo^qb kfqoldbk `lk`bkqo^qflk fk`ob^pba ^q bkbodfbp efdebo qe^k 7222 hJ1hdTS. tefib qeb fk`ob^pb lc kfqo^qb kfqoldbk `lk`bkqo^qflk t^p pj^iibo qe^k ^jjlkfrj kfqoldbk ^q pfjfi^o `lkafqflkp arb ql dbkbo^qflk lc evaoluvi o^af`^ip qeolrde ^`lrpqf` `^sfq^qflk0
,)-
;]VMJUNV\JT[ WO JVJNZWKRL MRPN[\RWV
Ak^bol_f` afdbpqflk fp qeb jlpq ^mmifba mol`bpp clo pbt^db piradb pq^_fifw^qflk0 Ak^bo/ l_f` afdbpqflk ib^ap ql piradb j^pp obar`qflk. abt^qbofkd fjmolsbjbkq. pq^_ib molar`qp molar`qflk. m^qeldbkf` jf`ol/lod^kfpjp abpqor`qflk ^ka _fld^p dbkbo^qflk0 Hltbsbo. ^k^bol_f` afdbpqflk fp `e^o^`qbofwba _v ^ pilt _flildf`^i abdo^a^qflk qfjb. tef`e obpriqp fk ^ ilkd cbojbkq^qflk mbofla ^ka i^odb afdbpqbo slirjb0 Ik qeb `^pb lc pbt^db piradb afdbpqflk. qeb evaolivpfp e^p _bbk fabkqf#ba ^p qeb o^qb/ifjfqfkd pqbm lc qeb mol`bpp [6]0
M^kv mobqob^qjbkq qb`ekfnrbp `^k _b rpba ql ^``bibo^qba evaolivpfp ^ka bke^k`b qeb ^k^bol_f` afdbpqflk mbocloj^k`b [5:]. [7]0 Teb ^fj lc qebpb qb`ekfnrbp fp ql _ob^h rm _^`qbof^i `bii jbj_o^kbp ^ka molar`b _fl/^s^fi^_ib pr_pqo^qb0 Tebpb mol`bppbp fk/ `irab qeboj^i. _flildf`^i. jb`e^kf`^i. `ebjf`^i tfqe lufa^qflk. efde mobpprob ^ka ^ih^if qob^qjbkqp0
#* #! 6?<DFK
piradb afpfkqbdo^qflk [48].[49].[53].[58]0 Ap pbbk fk m^o^do^me 303. riqo^plrkap. ^mmifba ^q 42/62 hHw cobnrbk`fbp fkql ^k ^nrblrp pvpqbj. bk`lro^db qeb cloj^qflk lc jf`ol_r__ibp qe^q dolt rm ql ^ `ofqf`^i pfwb ^ka qebk `lii^mpb0 Ttl `^sfq^qflk mebkljbk^ j^v _b obpmlkpf_ib clo qeb abpqor`qflk lc plifa `bii j^qqbo< mltbocri peb^o clo`bp ^ka plkl`ebj/ f`^i ob^`qflkp0 Seb^o clo`bp ib^a ql qeb afpormqflk lc `biip tfqe ^ pr_pbnrbkqiv obib^pb lc ifdeq lod^kf` pr_pq^k`bp fkql qeb ifnrfa pvpqbj0 Teb pr_pbnrbkq ^k^bol_f` afdbpqflk lc qeb afpormqba piradb j^v fjmolsb _fld^p molar`qflk tfqe ^ obar`b piradb nr^kqfqv0
,)-),
6VJNZWKRL MRPN[\RWV XZWLN[[ KJ[RL \QNWZa
Ak^bol_f` afdbpqflk fp ^ jriqfpq^db _fl`ebjf`^i mol`bpp qe^q fjmolsbp qeb `lksbopflk lc afpplisba ^ka m^oqf`ri^qb lod^kf` j^qqbo fkql jbqe^kb ^ka `^o_lk aflufab0 Mbqe^kb fp mo^`qf`^iiv klk/plir_ib ^ka fq bkap rm clo qeb jlpq fk qeb d^p me^pb. tebob^p `^o_lk aflufab fp jlob t^qbo plir_ib0 A m^oq lc fq fp j^fkiv flkfwba ql HCO!
' ^ka ^ pj^ii m^oq
ql CO&!' qe^q jfdeq bfqebo mob`fmfq^qb lo obj^fk ^p flk0 Teb afpqof_rqflk lc fklod^kf`
`^o_lk ql d^p lo ifnrfa me^pb fp pqolkdiv `lkqoliiba _v mH ^ka qbjmbo^qrob0 Tebobclob. fq fp lcqbk jlob obif^_ib ql abqbojfkb jbqe^kb mlqbkqf^i qe^k _fld^p mlqbkqf^i0
Teb _flildf`^i `lksbopflk mol`bpp l``rop tfqelrq buqbok^i bib`qolk ^``bmqlo pr`e ^p luvdbk ^p fk ^bol_f` mol`bppbp lo kfqo^qb1prime^qb ^p fk ^kluf` mol`bppbp0 A tfab o^kdb lc jf`ollod^kfpjp `^q^ivwb qeb mol`bpp fk qeb ^_pbk`b lc luvdbk0
Ak^bol_f` afdbpqflk `^k _b afsfaba fkql clro pq^dbp0 Drofkd qeb #opq pq^db. plifa `ljmibu lod^kf`p +`^o_levao^qbp. molqbfkp. bq`0, ^ob _olhbk altk ql ilt jlib`ri^o tbfdeq c^qqv ^`fap. mofj^ofiv _rqvof` ^ka molmflkf`0 Teb ^`fa molar`qflk obpriqp fk ^ aolm fk mH0 Ik qeb pb`lka ^ka qefoa pq^db. lod^kf` ^`fa ^ka plir_ib kfqoldbklrp `ljmlrkap ^ob `lksboqba fkql ^`bqf` ^`fa. ^jjlkf^. ^jjfkbp ^ka pj^ii nr^kqfqfbp lc CO& ^ka H&0 Teb
mH qbkap ql fk`ob^pb0 Tebpb jf`ollod^kfpjp e^sb _bbk obcbooba ql ^p ^`bqldbkf` _^`qbof^ lo ^`fap clojbop0 Ik qeb i^pq pq^db. qtl dolrmp lc jbqe^kb clojfkd _^`qbof^ tloh0 Okb dolrm `lksboqp `^o_lk aflufab ^ka evaoldbk ql jbqe^kb<
'0&- 6+&' '+(- 4+&0
Teb lqebo lkb `lksboqp ^`bq^qb ql jbqe^kb ^ka `^o_lk aflufab< '+''00+' '+(- 4+&0
Sqbmp fk ^k^bol_f` afdbpqflk mol`bpp ^ob peltk fk Ffdrob 3060
,)-)-
HJZRJKTN[ RV#]NVLRVP JVJNZWKRL MRPN[\RWV
Teb ^k^bol_f` jf`ollod^kfpjp. `e^o^`qbofwba _v ilt doltqe ^ka ob^`qflk pmbbap. ^ob sbov pbkpfqfsb ql qeb s^of^qflkp lc qeb bksfolkjbkq `lkafqflkp0 Tl molsfab ^ eb^iqev bksf/ olkjbkq clo jbqe^kb/clojfkd jf`ollod^kfpjp. pq^_ib ^ka lmqfjrj lmbo^qfkd `lkafqflkp jrpq _b j^fkq^fkba0 P^o^jbqbop pr`e ^p mH. sli^qfib c^qqv ^`fap +VFA, `lk`bkqo^qflk. ^ih^ifkfqv. ^ih^ifkfqv1sli^qfib c^qqv ^`fap o^qfl. _fld^p `ljmlpfqflk ^ka qbjmbo^qrob ^ob crka^jbkq^i clo ^k^bol_f` afdbpqflk mol`bpp jlkfqlofkd0 E^`e m^o^jbqbo fp `loobi^qba
#!$! 0IC;8B<CH8AG D= 8C8<FD9@: ;@><GH@DC #+
Ffdrob 306< Teb clro pqbmp lc ^k^bol_f` afdbpqflk mol`bpp< 30 Hvaolivpfp 40 A`faldbkbpfp 50 A`bqldbkbpfp 60 Mbqe^kldbkbpfp
tfqe qeb lqebop< qeb s^of^qflk lc ^ pfkdib m^o^jbqbo. fc klq ^``ljm^kfba _v ^k lsbo^ii jlkfqlofkd lc ^ii lqebo m^o^jbqbop. fq fp af%`riq ql fkqbomobq0
N3
Teb mH fp rpba ql gradb qeb pq^_fifqv lc qeb ^k^bol_f` ob^`qflk0 A kbrqo^i `lkafqflk. ^p fkaf`^qba _v ^sbo^db mH s^irbp fk ^ o^kdb lc 807/907. fp `lkpfaboba kloj^i ^ka obmobpbkqp ^ molmbo _^i^k`b _bqtbbk qeb j^qbof^ip bkqbofkd ^ka ib^sfkd qeb afdbpqbo0
Teb mH s^irb fk ^ afdbpqbo fp bppbkqf^iiv abqbojfkba _v qeb mobpbk`b lc CO& fk qeb
ifnrfa jbafrj ^ka. qebk. _v fqp m^oqf^i mobpprob fk qeb _fld^p ^ka _v qeb sli^qfib c^qqv ^`fap ^ka ^jjlkf^ `lk`bkqo^qflkp0
Teb mH abqbojfk^qflk `^k rkaboifkb ^ pvpqbj fj_^i^k`b. _rq lkiv tfqe ^ `boq^fk abi^v obpmb`q ql qeb _r"bo jbafrj bslirqflk0 Ik c^`q. qeb mH `e^kdb fp bsfabkq tebk _f`^o_lk^qb e^p #kfpeba fqp _r"bofkd ^`qfsfqv0 Terp. qeb mH jrpq _fka qeb lqebo m^o^j/ bqbop pr`e ^p ^ih^ifkfqv. sli^qfib c^qqv ^`fap `lk`bkqo^qflk ^ka _fld^p
-JI@JHLHRV
Aih^ifkfqv obmobpbkqp qeb ^_fifqv lc ^ pvpqbj ql kbrqo^ifwb molqlkp ^ka fq fp rpr^iiv bu/ mobppba ^p `^i`frj `^o_lk^qb `lk`bkqo^qflk0 Teb ^ih^ifkfqv lc ^k ^k^bol_f` afdbpqbo fp bppbkqf^iiv abqbojfkba _v qeb mobpbk`b lc ^ _r"bo pvpqbj arb ql qeb `lbufpqbk`b lc ^jjl/ kf^. tef`e lofdfk^qbp colj qeb molqbfk abdo^a^qflk. ^ka _f`^o_lk^qb. tef`e obpriqp colj qeb afpplirqflk lc `^o_lk aflufab fk qeb jbafrj0 Teb fkqbo^`qflk _bqtbbk `^o_lk aflufab ^ka qeb ifnrfa me^pb molar`bp qeb pr_pbnrbkq cloj^qflk lc ^ _r"bo pvpqbj `lkpfpqp lc `^o_lkf` ^`fa ^ka ^jjlkf^0 Teb obpriq lc qefp fkqbo^`qflk fp qeb cloj^qflk lc NH(HCO'<
$" #! 6?<DFK
'0&- +&0( +'0!' - +#
+'0!
' - / +(#40 ( / +(+'0'
Teb mobpbk`b lc qefp p^iq. afpplisba fk plirqflk. ib^ap ql ^ efde ^ih^ifkfqv fk qeb jbafrj0 Tefp ebimp ql `lkqoli qeb mol`bpp fk `^pb lc ^ sli^qfib c^qqv ^`fap ^``rjri^/ qflk0 A tbii/bpq^_ifpeba eb^qba afdbpqbo e^p ^ qlq^i ^ih^ifkfqv lc 5222/7222 jdC^CO'1L
[5;]0
>MJ@RHJD 2@RRV -BHCQ #>2-$
Teb sli^qfib c^qqv ^`fap fkaf`^qbp afdbpqflk moldobpp0 Teb sli^qfib c^qqv ^`fap ^ob obmob/ pbkqba _v qeb dbkbo^i clojri^ R/COOH. tebob R fp ^k ^ihvi dolrm pr`e ^p CH'+CH&,70
Gbkbo^iiv. arofkd qeb ^k^bol_f` afdbpqflk mol`bpp. qeb evaolivqf` ^ka ^`fafcvfkd _^`qbof^ molar`b. sli^qfib c^qqv ^`fap fk tef`e R `lkq^fkp colj 2 ql 5 `^o_lk ^qljp +peloq/`e^fk c^qqv ^`fap,0 Teb `lk`bkqo^qflk lc sli^qfib ^`fap. rpr^iiv bumobppba ^p COD lo ^`bqf` ^`fa +A`,. abmbkap lk qeb qvmb lc pr_pqo^qb ^ka fq o^kdbp colj 422 ql 4222 jdA`1L0 Nlq qeb ^_plirqb `lk`bkqo^qflk _rq o^qebo qeb s^of^qflk lc `lk`bkqo^qflk fp q^hbk ^p ^ m^o^jbqbo lc pq^_fifqv0 A praabk fk`ob^pb fk `lk`bkqo^qflk s^of^qflkp fkaf`^qbp qe^q qeb mol`bpp fp pifmmfkd qlt^oa ^`faldbkf` o^qebo qe^k jbqe^kldbkf` mol`bppbp0
Gbkbo^iiv. qeb fk`ob^pb fk sli^qfib ^`fap fp arb ql ^k fk`ob^pb fk pr_pqo^qb il^a qe^q abqbojfkbp qeb ^``bibo^qflk lc qeb evaolivqf` ^ka ^`faldbkf` mebkljbk^0
>MJ@RHJD E@RRV @BHCQ&@JI@JHLHRV P@RHM
Sfk`b qeb `lk`bkqo^qflk lc sli^qfib c^qqv ^`fap ^ka ^ih^ifkfqv ^ob qeb qtl m^o^jbqbop qe^q pelt ^ jlob o^mfa s^of^qflk tebk qeb pvpqbj qbkap ql jlsb ^t^v colj pq^_fifqv `lkaf/ qflkp. qeb sli^qfib c^qqv ^`fap1^ih^ifkfqv o^qfl fp ^ rpbcri `lkqoli m^o^jbqbo0 Ic qeb sli^qfib c^qqv ^`fap1^ih^ifkfqv o^qfl bu`bbap 20:. jbqe^kb molar`qflk `b^pbp ^ka qeb afdbpqbo c^fip0 Aq 206 qeb afdbpqbo fp ^k rmpbq `lkafqflk0 A molmbo o^qfl clo sli^qfib c^qqv ^`fap ql ^ih^ifkfqv fp _bqtbbk 203 ^ka 2040
9PMCSBRHML @LC BMKNMQHRHML ME AHMF@Q
Teb jlkfqlofkd lc qeb _fld^p nr^kqfqv ^ka `ljmlpfqflk +^p jbqe^kb ^ka `^o_lk aflufab, fp sbov fjmloq^kq clo qeb `lkqoli lc qeb ^k^bol_f` afdbpqflk mol`bpp pq^_fifqv [5;]0 Dfdbpqbo _fld^p molar`qflk fp qeb afob`q obpriqp lc plifap abpqor`qflk ^ka fq fp afob`qiv obi^qba ql qeb `e^o^`qbo lc qeb fk$rbkq piradb cbba0
Bfld^p molar`qflk $r`qr^qbp tfqe fk`ljfkd piradb $ltp. piradb pqobkdqe. qbjmbo^/ qrob ^ka mi^kq lmbo^qflk^i `lkafqflkp0
Bfld^p `lkq^fkp jbqe^kb. `^o_lk aflufab. pljb fkboq d^pbp ^ka primero `ljmlrkap0 A qvmf`^i _fld^p `ljmlpfqflk fp peltk fk T^_ib 3050
Teb _fld^p molar`qflk ^ka `ljmlpfqflk ^ob `lkpq^kq tebk qeb mol`bpp fp pq^_ib0 A ab`ob^pb fk qeb qlq^i _fld^p molar`qflk ^ka ^k fk`ob^pb fk qeb CO& mbo`bkq^db j^v
#!$! 0IC;8B<CH8AG D= 8C8<FD9@: ;@><GH@DC $#
T^_ib 305< Bfld^p `ljmlpfqflk
Mbqe^kb 77/92) _v sli0
C^o_lk aflufab 52/67) _v sli0 Hvaoldbk primefab 422/6222 mmj _v sli0 Ekbodv `lkqbkq 42/47 MJ1j'
Iq j^v _b l_pbosba qe^q ^k bu`bppfsb pr_pqo^qb il^a moljlqbp qeb fk`ob^pb lc CO&
mbo`bkq^db fk _fld^p0 Teb fk`ob^pb lc CO& `lk`bkqo^qflk fp ifkhba ql qeb `e^kdbp fk
sli^qfib c^qqv ^`fap `lk`bkqo^qflk fk qeb jfaaib0 Ik m^oqf`ri^o. qeobb af"bobkq pfqr^qflkp `^k l``ro<
& ^ ilt `lk`bkqo^qflk lc VFA ^ppl`f^qba ql ^ efde _fld^p molar`qflk. fk tef`e qeb CO& fp fk qeb o^kdb lc 47/55). fkaf`^qbp qe^q qeb mol`bpp fp pq^_ib=
& ^k fk`ob^pb lc VFA `lk`bkqo^qflkp lsbo qfjb ^ppl`f^qba ql _fld^p molar`qflk tfqe efde CO&`lk`bkqo^qflkp fkaf`^qbp ^ moldobppfsb ^``rjri^qflk lc VFA fk qeb ob^`/
qflk jbafrj=
& ^k fk`ob^pb lc VFA `lk`bkqo^qflkp `lj_fkba tfqe ^ _fld^p molar`qflk ab`ob^pfkd j^v fkaf`^qb mol_ibjp lc fkef_fqflk lo qluf`fqv0
4LGHAHRHLF QSAQR@LBDQ
Teb ^k^bol_f` mol`bpp fp kbd^qfsbiv ^"b`qp _v s^oflrp pr_pq^k`bp +pr`e ^p ^jjlkf^. prime^qbp. eb^sv jbq^ip ^ka `^qflkp, tef`e `^k bsbk fkef_fq lo e^iq qeb mol`bpp fk `boq^fk `lk`bkqo^qflkp0 M^kv pr_pq^k`bp pqfjri^qb qeb ob^`qflkp fk ilt `lk`bkqo^qflkp0 Hltbsbo. ^p `lk`bkqo^qflkp fk`ob^pb. qeb b"b`q _b`ljbp fkef_fqlov0
M`C^oqv [62] obmloqba ^ _bkb#`f^i `lkqof_rqflk lc ^jjlkf^ fk `lk`bkqo^qflk o^kdba _bqtbbk 72 ^ka 422 jd1L _b`^rpb ^jjlkf^ fp ^k bppbkqf^i krqofbkq0 Dbmbkafkd lk qeb mH. fq `^k _b ^ipl qluf`0 Ik ^ t^qbo pvpqbj ^jjlkf^ fp mobpbkq fk qeb cliiltfkd bnrfif_ofrj bnr^qflk<
/ +(#- 0+! ' / +'- +&0
Aq mH iltbo qe^k 904. qeb bnrfif_ofrj pefcqp qlt^oap qeb cloj^qflk lc ^jjlkfrj flk0 Aq mH efdebo qe^k 904. qeb fkafppl`f^qb ^jjlkf^ `lk`bkqo^qflk fk`ob^pbp0 Teb fkafppl`f^qb ^jjlkf^ fp jlob qluf` qe^k qeb ^jjlkfrj flk0
Srime^qb `lk`bkqo^qflkp efdebo qe^k 422 jd1L bke^k`b qeb doltqe lc prime^qb/ obar`qflk _^`qbof^ tef`e ^ob `ljmbqfqlop lc jbqe^kldbkp _^`qbof^ clo H& ^ka ^`bq^qb
rqfifw^qflk0
Teb qluf`fqv lc eb^sv jbq^ip abmbkap j^fkiv lk `ebjf`^i clojp fk tef`e qebv ^ob mobpbkq rkabo ^k^bol_f` `lkafqflkp0 Hb^sv jbq^ip `^rpb ^k^bol_f` afdbpqflk c^firob lkiv tebk jbq^i `lk`bkqo^qflkp fk plir_ib clojp +cobb flkp, bu`bba ^ `boq^fk qeobpelia `lk/ `bkqo^qflk tef`e fp afob`qiv obi^qba ql afs^ibkq primefab flkp `lk`bkqo^qflk0
$$ #! 6?<DFK
/&7 :@RHM
Teb obi^qflkpefm _bqtbbk qeb ^jlrkq lc `^o_lk ^ka kfqoldbk mobpbkq fk lod^kf` j^qbof^ip fp bumobppba ^p C^o_lk1Nfqoldbk +C1N, o^qfl0 A C1N o^qfl lc 42/52 fp `lkpfaboba ql _b lmqfjrj clo ^k ^k^bol_f` afdbpqbo0
Ic C1N o^qfl fp sbov efde. qeb kfqoldbk tfii _b `lkprjba o^mfaiv _v qeb jbqe^kldbkp ql jbbq qebfo molqbfk obnrfobjbkq ^ka tfii kl ilkdbo ob^`q lk qeb ibcq lsbo `^o_lk `lkqbkq fk qeb j^qbof^i0 Ap ^ obpriq qeb d^p molar`qflk tfii _b ilt0
Ic qeb C1N o^qfl fp sbov ilt. kfqoldbk tfii _b if_bo^qba ^ka ^``rjri^qb fk qeb cloj lc ^jjlkf^0 Tefp tfii fk`ob^pb qeb mH s^irb lc qeb j^qbof^i0 A mH s^irb efdebo qe^k :07 tfii pq^oq ql pelt ^ qluf` b"b`q lk qeb jbqe^kldbkf` _^`qbof^i mlmri^qflk0
W^pqb ^`qfs^qba piradbp e^p ^ C1N o^qfl lc 8/380 Tl j^fkq^fk qeb C1N ibsbi lc qeb afdbpqbo j^qbof^i ^q ^``bmq^_ib ibsbip. j^qbof^ip tfqe efde C1N o^qfl `^k _b jfuba tfqe qelpb tfqe ^ ilt C1N o^qfl. f0b0 lod^kf` plifa t^pqb `^k _b jfuba tfqe pbt^db piradb0 9GVQHB@J N@P@KDRDPQ
Tbjmbo^qrob
Mbqe^kldbkf` _^`qbof^ ^ob fk^`qfsb ^q buqobjbp lc efde ^ka ilt qbjmbo^qrob0 Webk qeb ^j_fbkq qbjmbo^qrob dlbp altk ql 32$C. d^p molar`qflk sfoqr^iiv pqlmp0 Ttl qbj/
mbo^qrob o^kdbp molsfab lmqfjrj afdbpqflk `lkafqflkp clo qeb molar`qflk lc jbqe^kb< !%/,-'()($ .#+&% Teb jbplmefif` o^kdb fp _bqtbbk 42/62$C= qeb lmqfjrj qbjmbo^qrob
fp `lkpfaboba ql _b 57/5:$C=
"'%.*,-'()($ .#+&% Teb qebojlmefif` qbjmbo^qrob o^kdb _bqtbbk 77/82$C0
Aiqelrde qeb qebojlmefif` mol`bpp fp jlob b%`fbkq. fq fp `lkpfaboba jlob `ljmif`^qba fk obpmb`q lc _^`qbof^ ^ka qeb j^qbof^i obnrfoba clo q^khp ^ka mfmbp0
Ll^afkd R^qb
Tefp fp ^k fjmloq^kq mol`bpp `lkqoli m^o^jbqbo fk `lkqfkrlrp pvpqbjp0 M^kv mi^kqp e^sb obmloqba pvpqbj c^firobp arb ql lsboil^afkd. lcqbk `^rpba _v fk^abnr^qb jfufkd0 Ic qebob fp ^ pfdkf#`^kq ofpb fk sli^qfib c^qqv ^`fap. qeb cbba o^qb ql qeb pvpqbj pelria _b obar`ba0
Rbqbkqflk qfjb
Sq^ka^oa evao^rif` obqbkqflk qfjb fk efde/o^qb afdbpqbop fp 37 ql 42 a^vp0 Hltbsbo. ^ tbii/jfuba ^ka eb^qba afdbpqbo j^v molar`b dlla nr^ifqv afdbpqba piradb ^cqbo 32 a^vp obqbkqflk qfjb0 Vli^qfib plifap obar`qflk e^p _bbk ^`efbsba fk j^kv afdbpqbop ^cqbo 32 a^vp obqbkqflk qfjb [63]0
Mfufkd1Adfq^qflk
A ibsbi lc jfufkd fp obnrfoba ql j^fkq^fk qeb mol`bpp pq^_fifqv tfqefk qeb afdbpqbo0 Teb ^fjp lc jfufkd ^ob ql `lj_fkb qeb cobpe j^qbof^i tfqe qeb _^`qbof^. ql pqlm qeb cloj^qflk lc p`rj ^ka ql ^slfa molklrk`ba qbjmbo^qrob do^afbkqp tfqefk qeb afdbpqbo0
#!$! 0IC;8B<CH8AG D= 8C8<FD9@: ;@><GH@DC $%
Osbo cobnrbkq jfufkd `^k afpormq qeb _^`qbof^i `ljjrkfqv ^ka fq fp dbkbo^iiv `lkpfaboba qe^q pilt jfufkd fp _bqqbo qe^k o^mfa jfufkd0 Teb ^jlrkq lc jfufkd obnrfoba fp ^ipl abmbkabkq lk qeb `lkqbkq lc qeb afdbpqflk jfuqrob0
,)-).
7@C \N[\
Teb _fl`ebjf`^i jbqe^kb mlqbkqf^i +BMP, ^pp^v t^p absbilmba ^p ^ pq^ka^oafwba jbqela ql bpqfj^qb qeb riqfj^qb _flabdo^a^_fifqv ^ka ^ppl`f^qba jbqe^kb vfbia lc lod^kf` pr_/ pqo^qbp clo fkab#kfqb abdo^a^qflk qfjb [64]0 Ik mo^`qf`b. qeb abdo^a^qflk qfjb fp ab#kfqb ^ka qeb jbqe^kb mlqbkqf^i fp bpqfj^qba _v buqo^mli^qflk lc ^ jbqe^kb qfjb abdo^a^/ qflk `rosb0 Mbqe^kb mlqbkqf^i `^k _b bumobppba pmb`f#`^iiv mbo j^pp sli^qfib plifap ^aaba + 3CH(1hdVS, lo COD ^aaba +3CH(1hdCOD,0 Teb slirjb fp rpr^iiv bumobppba
fk pq^ka^oa mobpprob +3 ^qj, ^ka qbjmbo^qrob +2$C, `lkafqflkp0 Bv qeb p^jb t^v _fld^p
mlqbkqf^i `^k _b ab#kba ^p qeb riqfj^qb _fld^p molar`qflk0
Teb BMP fp ^k^ildlrp ql qeb _fl`ebjf`^i luvdbk abj^ka ^pp^v qe^q e^p _bbk tfabiv rpba ql abqbojfkb _flabdo^a^_fifqv rkabo ^bol_f` `lkafqflkp clo t^qbo nr^ifqv ^k^ivpfp0 Tefp jbqela e^p _bbk tfabiv ^mmifba tfqe jfklo jlaf#`^qflk ql abqbojfkb qeb riqfj^qb jbqe^kb molar`qflk colj ^ s^ofbqv lc cbbapql`hp0 Hltbsbo. qeb qb`ekf`^i ^mmol^`ebp fk qbojp lc mobqob^qjbkq lc qeb p^jmib. fkl`rirj. d^p jb^probjbkq qb`ekfnrb ^ka fk`r_^/ qflk s^ov pfdkf#`^kqiv colj pqrav ql pqrav [65] [66] [67]0
3@PKMLHW@RHML ME .69 KDRGMCQ
Tebob ^ob pbsbo^i k^qflk^i ^ka fkqbok^qflk^i pq^ka^oap clojri^qba clo abp`of_fkd ^k^bo/ l_f` _flabdo^a^_fifqv [68]0 Tebpb jbqelap `^k _b afsfaba fkql qtl j^fk dolrmp< ^ dolrm ab^ip tfqe qeb ab#kfqflk lc ^k^bol_f` _flabdo^a^_fifqv lc `ebjf`^i `ljmlrkap +ISO 36:75/3;;;. ASTM 7733/3;;6. ASTM 7432/3;;4. ASTM E 4392/4223. ISO 37695/4224,. tefib qeb lqebo dolrm ab^ip tfqe qeb _flabdo^a^_fifqv lc lod^kf` pr_pqo^qbp ^ka _fld^p molar`qflk +ISO 33956/3;;7. ISO1DIS 36:75/3;;;. UK Eksfolkjbkq Adbk`v 4227,0
Akdbifa^hf bq ^i0 [69]. fk `lii^_lo^qflk tfqe pbsbo^i pmb`f^ifpqp lc ^k^bol_f` afdbpqflk +TG/A_^f,. qofba ql e^ojlkfwb qeb ^k^ivpfp jbqelap0 Terp. pljb _^pf` drfabifkbp clo ^ obif^_ib ^ka obmolar`f_ib ^ppbppjbkq lc qeb ^k^bol_f` _flabdo^a^_fifqv qbpqp ^ob dfsbk _v qeb ^rqelop clo moljlqfkd ^ `ljjlk molql`li0
Sljb fjmloq^kq fpprbp ^ob obmloqba _bilt0 Ikl`ri^qflk
Teb fkl`rirj pelria _b l_q^fkba colj ^ crii p`^ib ^k^bol_f` afdbpqbo +jbplmefif` lo qebojlmefif`,0 Teb fkl`rirj pelria _b eljldbklrp ^ka i^odb j^qbof^ip lqebo qe^k _flj^pp +pqlkbp. mfb`bp lc tlla.0 0 0 , objlsba0 Bbclob pq^oqfkd qeb _flabdo^a^qflk qbpq. qeb fkl`rirj jrpq _b fk`r_^qba ^q ^ qbjmbo^qrob bnr^i ql crii p`^ib mi^kq fk loabo ql abmibqb qeb obpfar^i _flabdo^a^_ib lod^kf` j^qbof^i0 Teb fk`r_^qflk mbofla fp rpr^iiv colj 4 ql 7 a^vp0 Teb fkl`rirj pelria klq _b t^peba ql objlsb qeb obpfar^i pr_pqo^qb ^p abp`of_ba lk ISO 33956 ^ka ASTM E 43920
Ic qeb _flabdo^a^_fifqv qbpqp `lk`bokp pmb`f#` lod^kf` jlib`ribp. qeb _^`qbof^i _flj^pp pelria _b bumlpba ql qeb pr_pqo^qb ql _b abdo^aba fk loabo ql bifjfk^qb qeb fkqbocbobk`b
$& #! 6?<DFK
obi^qba ql pq^_fifw^qflk lc qeb _^`qbof^i mlmri^qflkp mobpbkq fk qeb fkl`rirj0 :TUJ[R[S HJZP\PZ_
Teb fkl`rirj nr^ifqv pelria _b `eb`hba _v mboclojfkd ^`qfsfqv qbpqp lk ^`bq^qb lo `biirilpb0 Teb fkl`rirj pelria e^sb ^ jfkfjrj pmb`f#` ^`qfsfqv lk ^`bq^qb bnr^i ql 203 dCH(/COD1dVSS#a clo prpmbkaba piradb ^ka 205 dCH(/COD1dVSS#a clo do^kri^o
piradb0 Teb slirjb lc fkl`rirj ql _b rpba fk qeb qbpqp `^k s^ov dob^qiv. abmbkafkd lk qeb ^`qfsfqv ^ka _flj^pp `lk`bkqo^qflk lc fkl`rirj ^ka lk `lk`bkqo^qflk ^ka _flabdo^a/ ^_fifqv lc qeb pr_pqo^qb0 Teb fkl`rirj ^aaba slirjb `^k _b iltbo fc qeb fkl`rirj fp `lk`bkqo^qb0 Hfde slirjbp ^ob kb`bpp^ov tebk ilt abkpfqv fkl`rirj +^p pbt^db piradb, fp rpba0 Teb ^jlrkq lc fkl`rirj pelria _b bklrde ql mobsbkq qeb ^``rjri^qflk lc sli^qfib c^qqv ^`fap lo ^`faf` `lkafqflkp0
:TUJ[R[S \UR[SL
Teb slirjb `^k _b bpqfj^qba _v ^ pfjmib j^pp _^i^k`b0 Hltbsbo. qeb evaolivpfp o^qb ^ka _flj^pp ^`qfsfqv jrpq _b hkltk lo bpqfj^qba0 Teb slirjb `^k _b abqbojfkba ^p cliiltp< 6478/<5<6> 7::6==-3 6 33478/<5<63. &478/<5<6 +30403, tebob<
& XSS fp qeb evaolivp^_ib pr_pqo^qb `lk`bkqo^qflk fk piradb +d1L,= & V fp qeb slirjb lc piradb fk qeb ob^`qlo +L,=
& he fp qeb evaolivpfp `lkpq^kq +a!%,=
& VSS478/<5<6 fp qeb VSS `lkqbkq fk qeb fkl`rirj +dVSS1L,=
& SMA fp qeb pmb`f#` jbqe^kldbkf` ^`qfsfqv +dCH(/COD1dVSS a,0
Bflj^pp `lk`bkqo^qflk
Teb fkl`rirj `lk`bkqo^qflk `^k s^ov fk qeb o^kdb 20: / : dSV1L [6:]0 Sljb ^rqelop ob`ljjbka ^ `lk`bkqo^qflk lc. ^q ib^pq. 7 dSV1L. tebk qeb o^qb lc pr_pqo^qb objls^i fp ibpp qe^k 204 dCOD1dSVa0 A obar`ba s^irb lc 307 dSV1L `^k _b rpba clo piradb tfqe efdebo ^`qfsfqv0 Teb ISO 33956 pq^ka^oa jbqela prddbpqp ^ _flj^pp `lk`bkqo^qflk fk qeb ob^`qlo _bqtbbk 3 ^ka 5 dSV1L0
Sr_pqo^qb
Tlq^i plifap. sli^qfib plifap. COD. ^jjlkf^ ^ka melpmelorp lc qeb pr_pqo^qb pelria _b ^it^vp abqbojfkba0 Teb abqbojfk^qflk lc COD clo ebqboldbkblrp plifa pr_pqo^qbp fp rpr^iiv af%`riq ^ka q^hbp pljb rk`boq^fkqfbp [6;]0 Sljb ^rqelop e^sb efdeifdeqba elt qeb m^oqf`ib pfwb lc qeb pr_pqo^qb j^v fk$rbk`b qeb BMP abqbojfk^qflk [72][73] ob`ljjbkafkd ^ pq^ka^oafw^qflk lc m^oqf`ib pfwb ql fk`ob^pb qeb obmolar`f_fifqv lc qeb BMP qbpq0
#!$! 0IC;8B<CH8AG D= 8C8<FD9@: ;@><GH@DC $'
?XNHTPJ SHZZLX JUTJLTZXHZPUT
Teb fkfqf^i `lk`bkqo^qflk lc lod^kf` j^qqbo prddbpqba _v qeb pq^ka^oa jbqela fp o^qebo ilt ^ka bnr^i ql 322 jd1L ^``loafkd ql ISO 339560 Hltbsbo. ql jb^prob pfdkf#`^kq lsbomobpprobp. fc obibs^kq fkef_fqlov mebkljbk^ ^ob klq bumb`qba. qeb `lk`bkqo^qflk `^k _b pfdkf#`^kqiv fk`ob^pba rm ql 4/407 dCOD1L0
F1I o^qfl
Teb obi^qflkpefm _bqtbbk lod^kf` j^qqbo ^ka fkl`rirj. ab#kba ^p Fbba ql Ikl`r/ irj o^qfl +F1I,. ^"b`qp qeb aro^qflk lc qeb afdbpqflk mol`bpp +ab`ob^pfkd tfqe F1I, ^ka qeb qlq^i ^jlrkq lc _fld^p molar`qflk +ab`ob^pfkd tfqe F1I,0 Tebpb ^pmb`qp prddbpq ql jfkfjfwb F1I s^irb0 Hltbsbo. fc F1I fp qll ilt. fq fp af%`riq ql afpqfkdrfpe qeb _fld^p molar`qflk lc qeb fkl`rirj colj qe^q lc ^aaba lod^kf` j^qqbo0 A``loafkd ql Cevkltbqe bq ^i0 [74]. qeb lmqfjrj F1I s^irb lk sli^qfib plifap _^pfp pelria _b 2070 A pfjmib jbqela ql bpqfj^qb qeb ^jlrkq lc piradb obnrfoba clo _flabdo^a^_fifqv qbpq fp ^p cliiltp<
7) >
76
3222& +30404,
tebob<
& X) fp qeb ^jlrkq lc piradb +dVSS,=
& V fp qeb slirjb +L,=
& X fp qeb COD lc qeb pr_pqo^qb ql _b qbpqba +jd1L,= & A fp qeb jbqe^kldbkf` ^`qfsfqv +dCOD1dVSS,0
Tefp `^i`ri^qflk fp rpba clo ^ #opq olrde fkaf`^qflk ^ka fq fp _^pba lk qeb ^pprjmqflk qe^q qebob ^ob kl ^`faf` `lkafqflkp ^ka ^ii qeb pr_pqo^qb fp `lksboqba fkql jbqe^kb fk ^ pfkdib a^v0
Bfld^p
Teb qeblobqf`^i _fld^p molar`qflk. lo jbqe^kb. fp ^ rpbcri fkcloj^qflk arofkd mobm^/ o^qflk lc qeb qbpq ql bkprob qe^q qeb fkslisba ^jlrkqp ^ob klq bu`bppfsb lo qll mllo clo qeb jb^probjbkq pvpqbj0 Teb jbqe^kb molar`qflk. l_q^fkba colj fkl`rirj. pelria _b pr_qo^`qba colj qeb jbqe^kb molar`qflk ob`loaba fk qeb pr_pqo^qb qbpqp0 Tefp fp qeb `lkqoli ^ka `^k _b `^oofba lrq fk qofmif`^qb clo pq^qfpqf`^i pfdkf#`^k`b0
Mbafrj
A jbafrj `^k _b rpba ql `lsbo krqofbkq ab#`fbk`v fk _flj^pp0 P^oqf`ri^o ^qqbkqflk `^k _b q^hbk ql jbafrj _r"bo `^m^`fqv. tef`e jrpq _b molmloqflk^qb ql qeb ^jlrkq lc ^`fap qe^q ^ob bumb`qba arofkd qeb evaolivpfp pqbm lc qeb afdbpqflk mol`bpp0 Ic qeb ^`fap ^ob klq ^abnr^qbiv _r"boba. qeb mH aolmp ql s^irbp qe^q ^ob fk`ljm^qf_ib tfqe qeb jf`ol_f^i ^`qfsfqv ^ka klq obmobpbkq^qfsb lc qeb ob^ifqv lc qeb ^k^bol_f` mol`bpp0