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ELEMENTAL CHARACTERIZATION OF POTENTIAL ATMOSPHERIC DUST SOURCES OF VICTORIA LAND (ANTARCTICA, ROSS SEA SECTOR) BY NEUTRON ACTIVATION

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ELEMENTAL CHARACTERIZATION OF POTENTIAL

ATMOSPHERIC DUST SOURCES OF VICTORIA LAND

(ANTARCTICA, ROSS SEA SECTOR) BY NEUTRON

ACTIVATION

G

IOVANNI

B

ACCOLO

*

1,2

, C

ARLO

B

ARONI3

, M

ASSIMILIANOCLEMENZA2,4

, B

ARBARA

D

ELMONTE4

, V

ALTER

M

AGGI2,4

, A

LESSANDRA

M

OTTA2,4

, M

ASSIMILIANO

N

ASTASI2,4

,

E

ZIO

P

REVITALI2,4

, M

ARIA

C

RISTINA

S

ALVATORE3

1Università degli Studi di Siena, Siena, 53100, Italy 2INFN, sezione Milano-Bicocca, Milano, Milano, 20126, Italy

3Università di Pisa, Pisa, 56126, Italy

4 Università degli Studi di Milano-Bicocca, Milano, 20126, Italy

giovanni.baccolo@mib.infn.it

Recent investigations carried out on the Talos Dome ICE core

(TALDICE) revealed the presence of a local fraction of mineral dust

entrapped in the ice [1-4]. Several evidences point to the ice-free

areas of Victoria Land as possible sources. Here the elemental

composition of 40 samples of mineral sediments collected in

correspondence of ice-free areas of the Victoria Land is presented [5].

The geochemistry of samples was determined by Instrumental

Neutron Activation Analyses (INAA), which allowed quantifying the

concentration of 36 elements, spanning from major to trace elements.

Two different sample irradiations and 5 data acquisitions were

necessary to measure the maximum number of elements. Geochemical

results and principal components analyses suggest that the most

discriminating elements are the rare earth elements (REE) and

incompatible/compatible ones in respect to iron, in accordance with

the different lithological composition of the samples. Evidences of

chemical weathering were also recognized despite the extremely cold

and dry climate of these areas. The characterization of the Antarctic

potential source areas of atmospheric dust is the first step in order to

identify the active source areas in respect to Talos Dome and to

reconstruct the atmospheric trajectories followed by air masses in the

different climatic periods.

1 Delmonte, B., Baroni, C., Andersson, P.S., Shoberg, H., Hansson, M., Aciego, S., Petit, J.R., Albani, S., Mazzola, C., Maggi, V., Frezzotti, M. (2010). Aeolian dust in the Talos Dome ice core (East Antarctica, Pacific/Ross Sea sector): Victoria Land versus remote sources over the last two climatic cycles. Journal of Quaternary Science, 25:1327-1337

(2)

2 Albani, S., Delmonte, B., Maggi, V., Baroni, C., Petit, J.R., Stenni, B., Mazzola, C., Frezzotti, M. (2012). Interpreting last glacial to Holocene dust changes at Talos Dome (East Antarctica): implications for atmospheric variations from regional to hemispheric scales. Climate of the Past, 8:741-750

3 Delmonte, B., baroni, C., Andersson, P.S., Narcisi, B., Salvatore, M.C., Petit, J.R., Scarchilli, C., Frezzotti, M., Albani, S., Maggi, V. (2013). Modern and Holocene aeolian dust variabilità from Talos Dome (Northern Victoria Land) to the interior of the Antarctic ice sheet. Quaternary Science Review, 64:76-89

4 Lanci, L., Delmonte, B. (2013). Magnetic properties of aerosol dust in peripheral and inner Antarctic ice cores as a proxy for dust provenance. Global and Planetary Change, 110:414-419

5 Baccolo, G., Baroni, C., Clemenza, M., Delmonte, B., Maggi, V., Motta, A., Nastasi, M., Previtali, E., Salvatore, M.C. (2013). Neutron activation analysis on sediments from Victoria Land, Antarctica: multi-elemental characterization of potential atmospheric dust sources. Journal of Radioanalytical and Nuclear Chemistry, 10.1007/s10967-013-2851-x

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