Gli isotopi stabili nell’acqua fra suolo, pianta e atmosfera / Stable isotopes in the water within soil vegetation and atmosphere

Testo completo

(1)GHIJHKLMNLOPLQLRSTUVWXYZ[SVWP\L]P^_LPàbc01def. ghijk1lmneo0opqmirsthurpnl1fmnm01ef. vwJLJxyzy{JLxz|}JwJLMHww~||L|Lxywy_L{J|Mz|LHL|zyxH|. aHL P | M H x | L | M H w w | J | M J H w H L H M M | ¡¢££ ¤¥ ¦§¨¢¢§©ª©§¢ª ¡¢« ¬i®¯ih°®jk1lkgi®±²u®knl1f³k´®rrs¯ih°®jµo1k¶®°°sihknl1·. ,#%&!#0%'"'!<$%1'=1%,%"%.)(%& 2345679 3

(2) 7 9 37437939 &!(#! #!*,%#$%4;!&);4,%-.(%&!. 96773439 4 43

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¹us°®ºsmºs°g®»»sui¼½°i²¯mir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¸. 01.

(4) 01234566278 5 5332. !"#$%" &$"'( %()""($"*#"$()$+",)($+ "("*)"$-"*./)"!)$( !$$%!#"'(&")$$)0!!1!2 (%"')*")"0$+)""*&")"*!!1 34%")""!1(')$(%&")(()'" )&.,"()0(5%")*(()!)%*)" %"%")*((5&!)!#"4%"*%"'2 '($*$4%")3''&"*($"2 *#"*$$)678)''9:;<=>0

(5) ?@AB.C')" *((5$4%D%"!)6""((&((($(0" 4%")$"*#"$$)"))'))"'( %()""%4%)%))())%!0--" $"")")6'&)6*&0$%"**'$$ (@?E*((!!(#"%!78)"9:;<=>0

(6) ?@FB. G33")(3%)%3*(')((5%*((5$4%0 (5H""I%!+!%--($)0'6((5"#*((2 (""0(/))&J%*K$4%7I%!" L%")M0

(7) ???B'%)*%"*()*))2 &&()3"))'*'%)!33")( $$)6$+ $)(($)6*5$4%78)" 9:;<=>0

(8) ?@FB.,"4%)$"))D"*!"-($2 !"*3(% *$"'($)'$+'(2 -(")!!")"(''$"%* $4%7NO)PO"""0

(9) ?@

(10) B. ,)**!#"*$$)!)%* ($$(*((5$4%"*&.J%)(&*"2 )D3$(##)%(()$"$-)%((5"(*'( )!)-(**'"7NB '"7QB$+ $!"'"(($(*((5$4%.R()!)-2 ($"")"*'%*))")(*)"*(2 (5$4%'%"*3(% *$"()!")2 %(2)3"$+4%"* """*))2 ")%-(.R()!*Q*N"")* 4%%"$(7R%4%"*S+")"0@T

(11) TUHM9: <=>0@TV

(12) B((%$)$$")-")(!%W 3))(!""5 ?*($($ 7I!)""*PM*0@T VB.8--"()%") !"$!!(5"(*'()!)-(0(!))2 )* )!$0"$$(#"4% "&)*4%))")5""0("'(%()@?2@ ""$$D ))((&(%!!*%""%&)$2 "('0(!)))("3 0$+) *"*%""%&!")((5%*'()!)-( "((5"(-")("(()%**()!) *(('"*3(% *$")' 7X("O0

(13) ?@

(14) UC9:;<=>0

(15) ??YB. C5'")!%W-)$%"!()2 )%0!*$"&"$(())*((5%)()6 *%)(##'()!)-(!)%*($$(*(2 (5$4%""(")")%(0*& D'6.

(16). ))!")*))0"$+") '0*&(!)"#()6*4%))$"$" "$"'"!)*!(. Z[Z\]^^^_\à\ b9cdedfdged;9;hed:i;jd;kdlhm< R()!")*%") (")$+ ! ''"%"*&"%*"%)".R()2 !&"'"*3"))-(4%"*("%*!)" "%)"""$-"()!.G$+n"%)" ((5")"*((5)"!)$((())$") "%)0*%)!*(() (")")"'" () $$+""%"*&"%* 7KB.,("%* D! *((*( "%*"%)"7oB*!)"7p0!)$(($2 $+!)&")B*D!))$!$") *(-($+$. C($(*$4%D3)**%)*N *%"*@Q.C5

(17) *'"+*%)!)-(*2 '")$"NN$+$")"'"!))&") (%"!)"!!%%"!)"*%""%)". J%)5%())!)-(D")"$+$*%2 ).C5@F'"$")"@YA!)"!%W&@YY "%)"7QB0T"%)"7QB0@?"%)"7QB. ,"%"($(*$4%! "&)%))( ! -($-"#"0@A"$+($%"7!! 4%(($+$")"'"QB"!1*()* ()&"'")$%)"'()%*$+$"*" '()!.K$%*(( *&0'()!* %"(")+""3#*('*&*$"2 '%"#! "&$!)")$+$23$ *&. C$!#"")!)-(*(")* - )$4%((5Q(5ND!))")2 "*&(()&*%")"***$!#2 ")!$").J%)")#"0(q*()! ((r7stBD$($()$"*(54%#"@u s7tBw7v$!v)""2*v*)"**Bx@??? 7I4.@B *&v"*$(!!))(5)!!1!") 4%((!1(''7

(18) Ny@N@YQy@FQB.,"!)$0( &(s!*4%")!)!(((!!) )!$*$)*(() !!)"%")"2 ***3")$"$!#")!$"). ,()&*((5%)(##*)(")#"*"( 3))$+(*33"#)*%)!*

(19) %"@(")D ()!$$(7"((5$4%(!!)NyND!!2 @F)&")%'%(?.???@ AF(!!) @YQy QD!! )&")?.??

(20) ??

(21) B!$% %)(##(!!)v!($+--("''.

(22) 01224565724689212 11

(23) 8 8. KLMNOPQMRSQTPUOVPTPWOXP ,'& ") '++&&7 &'&+&&) 57#H&4+) '+Y'7&77 &&&&') !=4&" &># Z%5-'&++ "&=+) '-&'-&>#,5&&- +Y&+&' 7!7&&77#,7) 7&77+7&'' *5&&#$A & A&./%5=4B ./0&&B 0>!*7&'' 7!..2&%5!& *77=B 0>-&7'' ++*#@& -& "&5.27&&&-) 5!70+./*) &5!70-& '&&&) Y77!7 %55#,-774) '&&&-774') &#H-&%5-&) '77%7A. &&&4 %=B1B>&%&&7&&./.&24 &.F[*&%=010>#@ '*7&&&! '&& \=.]]2># ?&&&!) '&9'%) 5"'%5"=') ># KLMNOPQMRSQTPUM^^_SàOÔbLOP ,'%5" ) &"'7&+) &-&!c+Y'+& &4#H& ! &7 & 7&' 7& &&! '&7#8' d7#.)e7'' %5"-%&*&& +&+(# KOfgUhUiUjSLRVUXPRRPQ^kUaVSlUTPUXPRWMLSUlOmmSLSQTUnMâSVUPmUogU &77&&&'. !"" #$%&'(&) '*+&"#,-%& ) +&!&""*) +./&&.2#,-&) 010 & *.2&&&& ./0 0# 3+(&+! &) &4*5 &-4! 4!%&) &&&#6+&-+ (7+! &) &4*"&&5&5! 4 +%& &&&#8+&+7) & +(9) !1 +&&:*&+1* 7+:771:*;&<1*;77) <=7#.># ?&&+&&') +&#@577& &"7! A7./) %5-&&77=B0>- ;&&"%5<-& 4 &6CD0E=6 CD0E>- ''AFF2 6CD0EA!-'-!+ (FG#H&&4 %,I?7JI7J=,I?I>&6-4&" "'7&&& &'&%5#. .

(24) 01234566278 5 5332. !"#$ % & !"'+, (.) !"*-/0 1!"* 2 3&1 2 +4+(&1)+0))) *-/0) 1)5 ')(1%$15 "6$"( $11% % " !"#*78"#(+9:+0;" $ %&#5 2" "&$ <=>?@AB>CDBEAFBABF>GGHDIJ@G@K=@AFLM@BDE@MAN ;"1%$ (&& "5 (%&#'!"5 ($#))")!"#1 )O& P%$5 2 )&#%Q 1%5 !"#())))&)5 %%1 !" ;" " "" )%&#!"5 #% 5 )) 2)5 ) 1% $ &% !""1 ) ( "&5 !"&%& "5 "#%5 1 2R%"S))") !"#'&%&5 %"& " &%1% !" 2&&##!"#T&% $!"1 "1 "(UV*V)(+94

(25) 06 UV*W0XY./5,Y+,-*U!.0 ')1% "5 &%$1"%""5 P&"1 2&5 (" !" Z+94+(Q)2"## "1 "&")1 . &Y+,-" !"Y/" *1).0*Q)(+94+0'!")1 (

(26) [[ !"& %( 1")2&"&.

(27). ")" !"% Y./*W0X,Y+,-\+[*U!]0 2$1 !" 2*)(^GAK>GF_DEDA=@MF`>ED=Fa@BD( b7cO0O%!" !" %( "&$,(&1"% " %&15 O !" & UV"&( 1 ($) 1% 2&&) "&%d&UV &&"1% 2" #+,*."%0% %Y -Y/ e 2RUV$1"%"P5 " )(" "1) & !" 21 !" 2 "%e" &) "%% !" 2 *aAM>GF_DEDA=@MF`>ED=Fa@BD(O7cO0 2 &%&,& &+[WO ' O)f*.[[]0Z)1 1)".( !" )1) # 2R& (!" ) % 2R 2 V&%%b7cO( $ "%%( 5 &1 1&&*1).0 e(U"" ( 5 % %%&UV& !" b7cO&")g &UV 1"%5 &# 7 hE@G@EiFjDkG@F@lAEAm@FlE>K@G@FjDGGH>MIJ>F@BFlEJj@FDMAn@o l@AGAk@M@FDjFDMA@j=AGAk@M@ b#/-(!" " !"(" ) "%% & P1"5 !"#'()# !" &&( "% 2 !""S"#"5 %(1%"( 5 %"(#.

(28) 01224565724689212 11

(29) 8 8. F%6,- $!"$!;<! (#J6K, J8LM%@ !(#!$*=/G@+%NJO! !O"*(#P#+'!! !O*;(#P#+%Q#!<!" C>=/G@*;#+!;#!<!" =/G@*+%R##=/G@*+'!#! !*+% STU52V2W2XYZ0[31TY2\0]\0^0_131T`_2à2a3Y1`\^2b010\[T_T_U21Z02c3\T3dT4T1e2à21Z02T^`1`]TY2Y`[]`^T1T`_2à2f310\2T_21Z02gVhigjkl2^]3Y052mZ0 d43Yn24T_02T_bTY310^21Z02U4`d342[010`\TY2f310\24T_02opqrst52q`\02_0U31Tc02c34u0^2à2g23\02`d^0\c0b2T_2Y`4b2^03^`_^23_b2\0UT`_^2oZTUZ 040c31T`_23_b2431T1ub0tv23_b2T_43_bv2fZT40240^^2_0U31Tc02`\2]`^T1Tc02c34u0^23\02`d^0\c0b2T_2f3\[2^03^`_^23_b2\0UT`_^v23_b2`_21Z02Y`3^15 hTUZ231[`^]Z0\TY2Zu[TbT1e2b010\[T_0^2wx2c34u0^24`f0\21Z3_21Z02pqrs2od4u02b3^Z0b24T_0t2fZT4024`f231[`^]Z0\TY2Zu[TbT1e2b010\[T_0^ wx2c34u0^2ZTUZ0\21Z3_21Z02pqrs2o\0b2b3^Z0b24T_0t52wc3]`\31T`_2Y3u^0^232b0cT31T`_2a\`[21Z02pqrs2oU\00_2^`4Tb24T_0tv2fZTYZ2T^2[`\02`\ 40^^20[]Z3^Ty0b23YY`\bT_U21`21Z020c3]`\31T`_2\3102oU\00_2b3^Z0b24T_0^t52. !"##$!%&' #! (# )!"'*+!'$!, '"''' "%-!'(#. #$! */$!!012345'6789:&012345'6789+%& ! ''; ! )!!), (#;"', "#'(#" ))(#$"! #)(#'! , )(##'! "'(## #;<(#"*/=# />'677?+%@)#(## ".), )A7##,. ))(# *>BC$'8AA8:C$>B' 8AA6+%>'.#, ##!(#!, "<! ##) , ;)(# *-$"#D#E'678?+'##! !, #!) *FC$'8AA8+# ! (#(# *G!012345'677H+%I#!') ;)(#'#!;, ;!*, #;+'.# ))!" "'#)!' "!)"")#, ';<, ! ))(#; '!!# .

(30) 01234566278 5 5332. ! "#$%&'()**)+, #$%&'( )*-*./01 11 2 3 14. 3 115 32 53 3 1 33 5///. 31 61 2 533 7 6 318+. 8 3 36 9 3 3 : 9 3 +.9 52 5 +.93 33 313 6112 5 655, #$%&'()*-*./ ;$<=>#?$@%A@%>@B=<& C3 1 66 5 3 3 DEF0 GBH$HI#JK&$@H%L&BB%;I#M$<H>#$<N.33 5 2 OP*/ Q 933 1/R./D 33 55 31 3 3 3 7 3 53 33 S >TU/D13 2 3V 33W X/Y 2

(31) 1 333V-* ./ DDEF0 33Z 55 1 /[DEF093 159-. 55 5+). 1 3 7 62 55 5 + R. 1532 7\7 3/ D3V5A=&' @?'#$1MH?$@?=H=B%]'H^+QW2DEF0./ _3 333 3 2 H]]J'@?#. 6DEF0 /` 92 33 8 3/Y 3V 91 31 3 33 5 3 2 6DEF0/_ 6 6 2 31 3Za&BJb#?Mc%355 2 $c#<>&'%MH?d#<B@H?%#'#>#?$&'%&?&'NU#<YQ2ef./ Da&BJb#?Mc55 3 3 3 3 2 8- g 331/P./D 3.

(32). W/R207 DEF0 j@a(%k%J%BMc#>&$@M%<#I<#B#?$&$@H?%H]%&?%@BH$HI@M%>&BB%BI#M$<H>#J $#<%lGKL;m(. 81 33 2 6DEF0/ D 31 3 )P 3 7 2 31 6 36 1 3 5 /[ 2 33 5 3 3 / D 3 1 355 YQSef.1/P.9 1 3 -P *hQ. 3 5 /D 33 1 6DEF0 36 / ;I#$$<H>#$<@&%'&B#< E 33 3 36 1 2 3 61 1/ ./D 93 5 DEF0/D 1 1 6 1 DE.7 55 31 6 / g 3 755 6 55 2 39 7 /_3 D #$%&'()*-*+i#$%&'()*-R. 1 7 37 5 35 37 3+ 755 5 33 3/g 35 2 368 7 3 1 /` 59335 2 5 33 3/.

(33) 01224565724689212 11

(34) 8 8. U$&V)W#%!*"XYZ'[!#(#*\/*!0X*!$#%#]!\^0#!)^0! _JàFbFcFdLefEOIgFLOhFijklmFLKFKgEF_LInoKpFNqFrIJEOIEFLOhFiEIgONoN`pFNqFKgEF_HEEFsOJtEHeJKpFNqFuNMEOcuNoMLONa. U$&)/ #!#(#*\/*!0X*!$#%#]!\^0#!)^0!&[###+Q#) ##Q#0!*$!*##*#&,*# !!*##(###Q#*##*# !*"!*!!##! !####0vw!$EKFLoa+xyzz{& _JàF|FcFDLeEHFeGEIKHN}EKEHFLKFKgEF_LInoKpFNqFrIJEOIEFLOhFiEIgONoN`pFNqFKgEF_HEEFsOJtEHeJKpFNqFuNMEOcuNoMLONaFigEFepeKE}FqNHFIHpNÈOJI hJeKJooLKJNOFNqF~LKEHFqHN}FeNoJhFeL}GoEeFenIgFLeFeNJoFLOhFoELtEeFJeFegN~OFNOFKgEFHJ`gKFNEOJÈHFEKFLoaF a. !"##!! #$%##$&'!!(#) ## !*! *+# !#! ,-./#0!#++#+!##%& 1 !## !# !) !*# ((# ! # !0#((# #!#0!*# !*") #!!#%!#+#!**+!# #0!&. 23453657589:;<773:=>?@>A5B5>C<:5A>8>@5=3:;<5 =>?@3485:5;45=5:<:?<8>;5:;5:=3?@5>C3?<C8>: DEFGHEIJGJKLMJNOJ *#0!**!!*# #*! #$#&P#!+! $#$!!#Q!! # R*!%##*!*"S((*#* $!*#&TR!0#* !# .

(35) 01234566278 5 5332. ! " '

(36) # $%&'()1'*! + ,-'./.0+2 -).31'.

(37) 0455/4('0''413

(38) 0 + ,1/4(06

(39) 410 +2 &7%81..3*49: :;<: <:=!% ;= =<: ; 45:; * :=&!;; ** ! = == 49:;! :%*%* %%;&** <:*:* :: ::4 >?@ABBCDDE@FDGH>EIGJ>DK47% : L! &%*:= L & L%*:=4 7=;;%" L : :4 >>?@ABBCDDE@MEID>ICIDGJ>DK49: :=! ;:: ;" :=: <:& : :%*;: 47 <:= ;:"49: ; = L <: L%% &;%4)*4N:!= : ;: <: ') L,49: L ! <:" : %=45 ;"OP%!4 >>>?@ABBCDDE@GJD>DQR>IC47=;;%;: ;;=<:.

(40). S%4)8!OP%!!% = $%k &'() * 4 W>HX@l@Z@mM^C]GD>MF@EB@nGdJC>H^@R>FD>JJGD>EIX@. %: : :%% : ;49:; ; OP%!&;%46*%:<: L . S%46$: ;:; ::: ;47 =<:" TU<: ; :! % TT<:: %TVU ; 45' : 4 W>HX@Y@Z@[EIMC\DQGJ@]ERCJ@EB@D^C@\_>IM>\GJ@BJQ`CF@aCDbCCI@bGDC_ ME]\G_D]CIDF@>I@D^C@FE>JZ\JGIDZGD]EF\^C_CX@cFEDE\C@CI_>M^]CID@>F >IR>MGDCR@ad@GI@eGf@GIR@RC\JCD>EI@b>D^@GI@e>fX@g^C@F>HI@ehf >IR>MGDCF@D^GD@IE@>FEDE\C@B_GMD>EIGD>EI@EMMQ_F@RQ_>IH@D^C@]EiCZ ]CID@EB@bGDC_@B_E]@EIC@ME]\G_D]CID@DE@D^C@IC`DX@gd\>MGJ@>FEDE\C iGJQCF@BEQIR@>I@D^CFC@ME]\G_D]CIDF@G_C@FÊbI@>I@DGaJC@jX.

(41) 01224565724689212 11

(42) 8 8 X%D#S($(!!&$!$!Y9ES($!(( 9$(%@ Z3[P,\,],^36_/,1.,0à)b32,*324/c,.1465,)6,0d/,e30/^,b1fa3^0f/60c,5/cb^)[/5,)6,0d/,.1221e)6_,0/g0,365,^/a^/c/60/5,)6,h)_P,iP,j324/c,3^/ )65)b30)*/,54/,01,0d/,d)_d,*3^)3[)2)0`,^/a1^0/5,)6,2)0/^304^/P,. k9$(!$(!&$! k?&%%9?! D m Q lUo l no J!$7!$! K$?"A:pqrnsQC 9 & $ N N $$"$? ( SJ=JG /0,32PCQNDFWU(T#Yt$"/0 K!"!'& ?#F#DF ?#Q#DNN J 32PCQNDE K!" ?#uM#QuQ ?#Q#DMFD J U(T#/Y0,32PCtQ$ND"FW/0v,32PCQwND/E0,32PCQNDNW S9" B$$$((( Y$ ?#Du#D ?##DN K/0,32PCQNDE J!$!&# ?#E#FM ?#uNQo#QED U(T#Yt$"/0,32PCQNDE !& J! 2PCwQN/D0E,32PCQNDNWU(T#Yt$" &$$$"!# ?#EN#DQu ?#FDQ#FE v / 0 , 3 9! J!x&! ?#Q#DD ?#FN#mM v /0,32PCwQN/D0E,32PCQNDNWU(T#Yt$" J!?9 ?ymFyDm zz {'&/0,32PCQNNm Y&| ?#Em#DNM ?#uM#MuN v /0,32PCwQN/D0E,32PCQNDNWU(T#Yt$" Y&K #mo #EEQo r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

(43) 01234566278 5 5332. ! " ! #$%& " "'! ! $ %' ! " "" "! " ( ) ' )$%" '" *$+,

(44) - .&&"$ % ' ") #! " " $/ 0 ! & $ *" 1 " ! ) ' "! &)$2)! " )! $3)# & & ) ' ! +456789:; ,

(45) -,.$%' # $ % ! '"" # + ".$<1 ! ! += >67 9:;-??

(46) . '! "! ) $*"" ' ) '@ ! +) ) ' .

(47). .# ! &A! '+= >6789:;-??

(48) .$ BCDEEDF9GDHI6 4 ) ' " ! $2 ) ' 1& & $2 ! )"! ' 1" +JKL,

(49) -MN/6789:;,

(50) - . "+O6789:;,

(51) -P.$%! ') '# "" ) '"A+=* ,

(52) - ."') '&! ) "$Q ) '& "! ' )' +"$M.$ BC9RST98UD8V9:U98 4 " '" ! 0) ' )$ 2) ) '"1&! ) 1"+WP

(53) X. +KY6789:;,

(54)

(55) .$ 3 'Z

(56) X Z-Z [\ ! & ! & '"" +]= >,

(57) -M.$<! & ) '" '" " + ! . "$ 2 '" '" A#" ! "" " 1"& ) ' " +^6789:; ,

(58) -M.$/1 && ) !.

(59) 01224565724689212 11

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`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

(61) 01234566278 5 5332. !"!#!!"! !$$$##% &'$#( )"!*#"$% "$"! +,-./01234

(62) 55 6(7 !$$#!$$!8 !$$""!$ !

(63) ":;# 9<(=""$ !$$&"!% !#$###% "! &$"()"!* #""$#:; #<+>./01234 :??@6(=!$"$#&& ###!#% #(A&'## !B"#"!!# C!"!$"#F +!"!F"" D9 6#% "#9

(64) F<9%&'#E#% #!#< ( % "!# ( #"!$% #!! "#$+)/01234

(65) 5: 6( "!"##! !*"##$ "'()"!"$

(66) 5:@ "*#!!##% "$#G.!HIJ0JK/L M2I/N1I0ONP/I1JQ1R20/S1K2S0P0PJTPTU12TN1K32T0LIJP3 PT0/S2V0PJTI1PT1QJS/I0/N12TN12USPVO30OS231/TWPSJTX/T0I ###!&# #=&'#>Y+Z"6( "#[\!"!% ##( "!& "!#!( "#* &##+( ]6"!8!^$# ^!8!#(_" &#$'##* "#+DG$Y/01234

(67) 5:@6(= "#"*#" "##"% $"#(7!B* ""#!% ##"*!% $$#!(="# '!"#&#!8.

(68). !!&!!#!" !#!*$ ##"!`<

(69) 9

(70) #!#% ""#U2ILM/TVa+b/0 234

(71) 55;6(=&*# "#!&!# +c.#/01234

(72) 5:E6( &#% !!!"*&!% !B""#"% """!( 7""#"! #&"##"!"( ,&## #&!"!#!#% "!!()"!d% e/0123(+

(73) 55@6" #!f g"/0123(+!!$$6 "#% f<G./0123(+

(74) 5: 6!% "$ "##( h""###% "$% *!$##"!% $()"!# *"!!"!8#% #"(7 !!#"% #'*##"! &KJJ3#&!$$"!^ ##&!#( A#"#*#!"% #&!# ()!!#"' !## *## "##"!"(i## !!+:6 !#&"!"#f +

(75) 6!"#% "!#"#f+j6 "#!"["#% ##\!!&!!! "( kl2VmO21T/3321W/U/02nPJT/ )8#]5o#" #"&$!& $"#! +e./01234

(76) 5:j6( #"% "!##".

(77) 01224565724689212 11

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

(79) 01234566278 5 5332. !!!!! "#$%& !!&! !!!'(%'!! !!)!! !%%'! %"!# *+ ""!"! !!!'!! ,-./012345&6789:#;& &+!<=!% '!!!!!" %%)!!% '!!)! !(!&!%% !+!&!'& !'&!!! "!%% # >%!&'!? !!!%!' '!%!! !!%#@!! !!""&!% '!!!&'!! "!,%# :#*+!(!! %%"('! %!# A!!'&!! !+!+''! &!! !!""!"%&"%'!! ! !'! + & %% "%,&'! B:,& '!'!!!:# ;!+ '!""!" %%+"+! +!!!!% %"! ! "!!%%'! +#C! !%%" '!&! "!"!! !'!? #D"& +!!!!!! !!'%%! %!!+!'!E# ;%%%%'!! '!&+!!.

(80). ""'! "+"'!?!! !%%,F012345&677

(81) :#G!! ?!!#H!%& !!+"! !! ""! ''+!%!'"'!!# I!!&" %%E !!#H!%+! %!!!!! !+" !!! !#H!? &%+& +!!%% !!+0JJK2LMN3OP3QL0!!! !!%" %% "+,R%%012345&6787:# STUVWXYZTUZ[ R +!+! !!!!!%% %!!! "'!%#*+ !'' !'&"!! !#@&!! !?!" %!!!! !!&%! !%%! #*+!& !%&%%!!!!? !%!& "#\&! '!!+ !%!'!+ ! ?!!% !%!!+%%!'+ ++!&"!" !!E!(%%! !!+?! %!&'! %"#H!&+'!+! !!!' % ! "#] "!!E !&%!!% +!" ! " (" %%!#;!!!"!!".

(82) 01224565724689212 11